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Trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato]dipyridine-cobalt(II) hemihydrate.

ABSTRACT: The asymmeric unit of the title compound, [Co(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa-hedral trans-[Co(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol-ecule and a half-mol-ecule of water, which lies on a twofold rotation axis. A three-dimensional network is generated by N-H?O and O-H?O hydrogen bonds between the complex and the water mol-ecules.

SUBMITTER: Wang YF

PROVIDER: S-EPMC2979022 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato]dipyridine-cobalt(II) hemihydrate.

Wang Yan-Fei YF Zou Hong-Li HL Luo Xu-Jian XJ Chen Zhen-Feng ZF Liang Hong H

Acta crystallographica. Section E, Structure reports online 20100421 Pt 5

The asymmeric unit of the title compound, [Co(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa-hedral trans-[Co(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol-ecule and a half-mol-ecule of water, which lies on a twofold rotation axis. A three-dimensional network is generated by N-H⋯O and O-H⋯O hydrogen bonds between the complex and the water mol-ecules. ...[more]

PMID: 21579035

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