Browse
Submit Data
Databases
API
Help

Dataset Information

9 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato]dipyridine-cobalt(II) hemihydrate.

ABSTRACT: The asymmeric unit of the title compound, [Co(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa-hedral trans-[Co(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol-ecule and a half-mol-ecule of water, which lies on a twofold rotation axis. A three-dimensional network is generated by N-H?O and O-H?O hydrogen bonds between the complex and the water mol-ecules.

SUBMITTER: Wang YF

PROVIDER: S-EPMC2979022 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato]dipyridine-cobalt(II) hemihydrate.

Wang Yan-Fei YF Zou Hong-Li HL Luo Xu-Jian XJ Chen Zhen-Feng ZF Liang Hong H

Acta crystallographica. Section E, Structure reports online 20100421 Pt 5

The asymmeric unit of the title compound, [Co(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa-hedral trans-[Co(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol-ecule and a half-mol-ecule of water, which lies on a twofold rotation axis. A three-dimensional network is generated by N-H⋯O and O-H⋯O hydrogen bonds between the complex and the water mol-ecules. ...[more]

PMID: 21579035

Similar Datasets

trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato]dipyridine-nickel(II) hemihydrate.

Project description:The asymmetric unit of the title compound, [Ni(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa-hedral trans-[Ni(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol-ecule and half of a water mol-ecule. A three-dimensional network is generated by N-H?O and O-H?O hydrogen bonds and C-H?O inter-actions between the complex and the water mol-ecules.

| S-EPMC2971836 | biostudies-other

trans-Bis[4-amino-N-(pyrimidin-2-yl-?N)benzene-sulfonamidato-?N]bis(N,N-dimethyl-formamide-?O)cobalt(II).

Project description:The title complex, [Co(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)], lies across an inversion center. The Co(II) atom is coordinated in a slightly distorted octa-hedral geometry by four N atoms from two bidentate 4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidate (sulfadiazine) anions and two O atoms from two dimethyl-formamide (DMF) ligands. The dihedral angle between the benzene and pyrimidine rings is 82.37?(13)°. A three-dimensional network is generated by N-H?O hydrogen bonds between the amino groups and of the sulfonamidate O atoms of neighbouring mol-ecules. The DMF ligand is disordered over two sets of sites in a 0.559?(4):0.441?(4) ratio.

| S-EPMC3515142 | biostudies-literature

Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato](1,10-phenanthroline)nickel(II).

Project description:In the mononuclear title compound, [Ni(C(10)H(9)N(4)O(2)S)(2)(C(12)H(8)N(2))], the Ni(II) atom has a distorted octa-hedral coordination geometry comprising four N atoms from two 4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidate ligands and two N atoms from a 1,10-phenanthroline ligand. In the crystal, mol-ecules are connected into a three-dimensional supra-molecular network via N-H?O hydrogen bonds and weak C-H?O and C-H?N contacts.

| S-EPMC3297286 | biostudies-literature

Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato](2,2'-bipyridine)manganese(II).

Project description:The title compound, [Mn(C(10)H(9)N(4)O(2)S)(2)(C(10)H(8)N(2))], contains a distorted octa-hedral [Mn(sdz)(2)(bpy)] (sdz is the sulfadiazine anion and bpy is 2,2'-bipyridine) complex mol-ecule. A three-dimensional network is generated by N-H?N, N-H?O and C-H?O hydrogen bonds from the sulfadiazine ligands.

| S-EPMC2979398 | biostudies-literature

catena-Poly[neodymium(III)-bis-[?-N-(dimorpholinophosphor-yl)benzene-sulfonamidato]-sodium(I)-bis-[?-N-(dimorpholinophosphor-yl)benzene-sulfonamidato]].

Project description:The cubic crystal structure of the title compound, [NaNd(C(14)H(21)N(3)O(5)PS)(4)](n), is composed of one-dimensional polymeric chains propagating in [100], built up from [Nd(C(14)H(21)N(3)O(5)PS)(4)](-) anions and sodium cations functioning as linkers. In the complex anion, the Nd(3+) ion has an eightfold coordination environment formed by the sulfonyl and phosphoryl O atoms of four bidentate chelating N-(dimorpholinophosphor-yl)benzene-sulfonamidate ligands: the resulting NdO(8) polyhedron can be described as inter-mediate between dodeca-hedral and square anti-prismatic. The sodium ion adopts an NaO(4) tetra-hedral geometry arising from four monodentate benzene-sulfonamidate ligands. The resulting crystal structure is unusual because it contains substantial voids (800?Å(3) per unit cell), within which there is no evidence of included solvent.

| S-EPMC2983777 | biostudies-literature

Bis[4-amino-N-(pyrimidin-2-yl-?N)benzene-sulfonamidato-?N](4,4'-di-methyl-2,2'-bipyridine-?N,N')cadmium dimethyl-formamide disolvate.

Project description:In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal-prismatic geometry arising from the two sulfadiazinate ligands and one 4,4'-dimethyl-2,2'-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethyl-formamide mol-ecule show disorder and were modelled with two different orientations and with site occupancies of 0.584?(10):0.416?(10). The geometry around the sulfadiazine S atom is distorted tetra-hedral. The crystal structure involves N-H?O hydrogen bonds which link mol-ecules into a three-dimensional network. Weak C-H?O hydrogen bonds are also observed.

| S-EPMC3297235 | biostudies-literature

Bis[4-amino-N-(4-methyl-pyrimidin-2-yl-?N (3))benzene-sulfonamidato-?N](2,2'-bi-pyridine-?(2) N,N')mercury(II).

Project description:The complete mol-ecule of the title complex, [Hg(C11H11N4O2S)2(C10H8N2)], is generated by crystallographic twofold symmetry, with the mercury cation lying on the rotation axis. The mercury coordination polyhedron can be described as tetra-hedral (from the N,N'-bidenate bi-pyridine mol-ecule and the sulfonamide N atoms of the sulfamerazine anions) or as squashed trigonal-prismatic, if two long (> 2.80?Å) Hg-N bonds to pyrimidine N atoms are included. The dihedral angle between the aromatic rings in the anion is 73.3?(2)°. In the crystal, N-H?(N,O) and N-H?N hydrogen bonds link the mol-ecules into a three-dimensional network.

| S-EPMC3998590 | biostudies-literature

Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato]-?N,N';?N-aqua-bis-(dimethyl-formamide-?O)cadmium(II) monohydrate.

Project description:In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)(H(2)O)]·H(2)O, the Cd(II) ion displays a grossly distorted octa-hedral (or irregular) mer-CdN(3)O(3) coodination polyhdron arising from its coordination by one N,N'-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion, two O-bonded dimethyl-formamide molecules and one water mol-ecule. A short Cd?N contact [2.890?(3)?Å] to the monodentate sulfadiazinate ion also occurs. The dihedral angles between the planes of the aromatic rings of the anions are 86.81?(14) and 68.65?(14)°. The crystal structure features inter-molecular N-H?O, O-H?O and O-H?N hydrogen bonds.

| S-EPMC3120478 | biostudies-other

catena-Poly[calcium-bis-[?-N-(dimethyl-phosphino-yl)benzene-sulfonamidato]].

Project description:The crystal structure of the title calcium complex, [Ca(C(8)H(11)NO(5)PS)(2)](n), is composed of a polymeric chain, which is formed due to two bridging sulfonyl groups linking Ca(II) ions in a O-S-O-Ca manner. Thus, the coordination environment of the Ca(II) ions is composed of six O atoms belonging to the phosphoryl and sulfonyl groups of two chelate rings and two additional O atoms of two bridging sulfonyl groups. The coordination polyhedron of the central atom (2 symmetry) has a distorted octa-hedral geometry.

| S-EPMC2970174 | biostudies-literature

Tris(N-{bis-[meth-yl(phen-yl)amino]-phosphor-yl}benzene-sulfonamidato-?2O,O')(1,10-phenanthroline-?2N,N')lanthanum(III).

Project description:The asymmetric unit of [La(C20H21N3O3PS)3(C12H8N2)] is created by one LaIII ion, three deprotonated N-{bis-[meth-yl(phen-yl)amino]-phosphor-yl}benzene-sulfonamidate (L-) ligands and one 1,10-phenanthroline (Phen) mol-ecule. Each LaIII ion is eight-coordinated (6O+2N) by three phosphoryl O atoms, three sulfonyl O atoms of three L- ligands and two N atoms of the chelating Phen ligand, leading to the formation of six- and five-membered metallacycles, respectively. The lanthanum coordination polyhedron has a bicapped trigonal-prismatic geometry. 'Sandwich-like' intra-molecular ?-? stacking inter-actions are observed between the 1,10-phenanthroline ligand and two benzene rings of two different L- ligands. The phenyl rings of L- that are not involved in the stacking inter-actions show minor positional disorder. Mol-ecules form layers parallel to the (010) plane due to weak C-H?O inter-molecular hydrogen bonds. Unidentified highly disordered solvate mol-ecules that occupy ca 400?Å3 large voids have been omitted from the refinement model.

| S-EPMC5499295 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data