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Cis-Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamido-?N,N']bis-(dimethyl sulfoxide-?O)cadmium.

ABSTRACT: The complete mol-ecule of the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(2)H(6)OS)(2)], is completed by the application of a twofold rotation axis. The Cd(II) atom is six coordinated by two bidentate sulfadiazinate anions and two dimethyl-sulfoxide mol-ecules. The resulting N(4)O(2) donor set displays a distorted trigonal-prismatic coordination geometry. The S atom and methyl groups of dimethyl-sulfoxide are disordered over two sets of sites, with site occupancies of 0.715?(4) and 0.285?(4). The crystal structure features inter-molecular N-H?N and N-H?O hydrogen bonds that lead to the formation of layers in the ab plane.

SUBMITTER: Hossain GM

PROVIDER: S-EPMC3099781 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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cis-Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamido-κN,N']bis-(dimethyl sulfoxide-κO)cadmium.

Hossain G M Golzar GM

Acta crystallographica. Section E, Structure reports online 20110326 Pt 4

The complete mol-ecule of the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(2)H(6)OS)(2)], is completed by the application of a twofold rotation axis. The Cd(II) atom is six coordinated by two bidentate sulfadiazinate anions and two dimethyl-sulfoxide mol-ecules. The resulting N(4)O(2) donor set displays a distorted trigonal-prismatic coordination geometry. The S atom and methyl groups of dimethyl-sulfoxide are disordered over two sets of sites, with site occupancies of 0.715 (4) and 0.285 (4). T ...[more]

PMID: 21754012

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