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1,10-Phenanthroline-dithio-oxamide (2/1).

ABSTRACT: The asymmetric unit of the title compound, C(12)H(8)N(2)·0.5C(2)H(4)N(2)S(2), contains one 1,10-phenanthroline mol-ecule and a half-mol-ecule of dithio-oxamide, which lies across a crystallographic inversion center. The 1,10-phenanthroline unit is not strictly planar, with dihedral angles between the central benzene ring and the pyridine rings of 1.42?(10) and 1.40?(10)°. In the crystal structure, two 1,10-phenanthroline mol-ecules are linked together by one dithio-oxamide via inter-molecular N-H?N hydrogen bonds.

SUBMITTER: Fun HK

PROVIDER: S-EPMC2979584 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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1,10-Phenanthroline-dithio-oxamide (2/1).

Fun Hoong-Kun HK Loh Wan-Sin WS Maity Annada C AC Goswami Shyamaprosad S

Acta crystallographica. Section E, Structure reports online 20100512 Pt 6

The asymmetric unit of the title compound, C(12)H(8)N(2)·0.5C(2)H(4)N(2)S(2), contains one 1,10-phenanthroline mol-ecule and a half-mol-ecule of dithio-oxamide, which lies across a crystallographic inversion center. The 1,10-phenanthroline unit is not strictly planar, with dihedral angles between the central benzene ring and the pyridine rings of 1.42 (10) and 1.40 (10)°. In the crystal structure, two 1,10-phenanthroline mol-ecules are linked together by one dithio-oxamide via inter-molecular N- ...[more]

PMID: 21579413

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