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ABSTRACT:
SUBMITTER: Alzaalouk AS
PROVIDER: S-EPMC3008025 | biostudies-literature | 2010 Aug
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20100828 Pt 9
Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio-carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa-hedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetra-meric supra-molecular aggregates mediated by C-H⋯S ...[more]