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Bis(N-isopropyl-N-methyl-dithio-carbamato-?S,S')(1,10-phenanthroline-?N,N')zinc.

ABSTRACT: The Zn(II) atom in the title compound, [Zn(C(5)H(10)NS(2))(2)(C(12)H(8)N(2))], exists in a distorted cis-octa-hedral N(2)S(4) donor set defined by two chelating dithio-carbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H?S, C-H??(ZnS(2)C) and ?-? [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955?(13)?Å] inter-actions.

SUBMITTER: Wahab NA

PROVIDER: S-EPMC3089284 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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Bis(N-isopropyl-N-methyl-dithio-carbamato-κS,S')(1,10-phenanthroline-κN,N')zinc.

Wahab Nor Asiken Abdul NA Baba Ibrahim I Mohamed Tahir Mohamed Ibrahim MI Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20110407 Pt 5

The Zn(II) atom in the title compound, [Zn(C(5)H(10)NS(2))(2)(C(12)H(8)N(2))], exists in a distorted cis-octa-hedral N(2)S(4) donor set defined by two chelating dithio-carbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H⋯S, C-H⋯π(ZnS(2)C) and π-π [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955 (13) Å] inter-actions. ...[more]

PMID: 21754288

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