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Bis(1,5-diphenyl-carbazonato)di-methano-lcobalt(II).

ABSTRACT: The structure of the title compound, [Co(C(13)H(11)N(4)O)(2)(CH(3)OH)(2)], is a mononuclear six-coordinated octa-hedral cobalt(II) complex of C(i) mol-ecular symmetry. The Co(II) ion is coordinated by two N atoms and two O atoms from two 1,5-biphenyl-carbazide ligands, and two O atoms from two methanol molecules. Two diphenyl-carbazidate ligands and the central Co(II) ion form the basal plane, with the two methanol mol-ecules located in axial positions. The crystal packing is defined by bifurcated O-H?N hydrogen bonding and intra-molecular N-H?O inter-actions.

SUBMITTER: Chen Y

PROVIDER: S-EPMC2979696 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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Bis(1,5-diphenyl-carbazonato)di-methano-lcobalt(II).

Chen Yanmei Y Xu Bin B She Shixiong S Hu Bin B Li Yahong Y

Acta crystallographica. Section E, Structure reports online 20100109 Pt 2

The structure of the title compound, [Co(C(13)H(11)N(4)O)(2)(CH(3)OH)(2)], is a mononuclear six-coordinated octa-hedral cobalt(II) complex of C(i) mol-ecular symmetry. The Co(II) ion is coordinated by two N atoms and two O atoms from two 1,5-biphenyl-carbazide ligands, and two O atoms from two methanol molecules. Two diphenyl-carbazidate ligands and the central Co(II) ion form the basal plane, with the two methanol mol-ecules located in axial positions. The crystal packing is defined by bifurcat ...[more]

PMID: 21579603

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