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Ethyl (E)-2-methoxy-imino-2-(4-nitro-benzo-yl)acetate.

ABSTRACT: The title mol-ecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxy-imino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 Å) and almost orthogonal [with dihedral angles of 99.44 (13) and -77.85 (13)°, respectively] to the carbonyl and nitro-phenyl groups which lie to either side of this central plane. The crystal structure is consolidated by C-H⋯O contacts.

SUBMITTER: Caracelli I

PROVIDER: S-EPMC2979917 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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Ethyl (E)-2-methoxy-imino-2-(4-nitro-benzo-yl)acetate.

Caracelli Ignez I Moran Paulo J S PJ Hinoue Luciana L Zukerman-Schpector Julio J Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100120 Pt 2

The title mol-ecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxy-imino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 Å) and almost orthogonal [with dihedral angles of 99.44 (13) and -77.85 (13)°, respectively] to the carbonyl and nitro-phenyl groups which lie to either side of this central plane. The crystal structure is consolidated by C-H⋯O contacts. ...[more]

PMID: 21579817

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