2,2'-Dithio-dianiline: a redetermination at 100?K.

ABSTRACT: STRUCTURAL STUDIES OF THE TITLE COMPOUND [SYSTEMATIC NAME: 2,2'-(disulfanedi-yl)dianiline], C(12)H(12)N(2)S(2), were previously performed at room temperature [Gomes de Mesquita (1967 ?). Acta Cryst.23, 671; Lee & Bryant (1970 ?). Acta Cryst. B26, 1729; Ribar et al. (1975 ?). Bull. Yugoslav. Crystallogr. Centre, A10, 68]. The results of the current redetermination allow a clarification of the nature of the intra- and inter-molecular N-H?S hydrogen bonding described in the literature for this compound. On cooling to 100?K, the unit cell contracts most in the c axis, and it changes rather less in the directions involving the strongly hydrogen-bonded chains, which are the a and b axes. In the crystal structure, N-H?N hydrogen bonds link neighbouring mol-ecules into two-dimensional frameworks parallel to the ab plane. An additional inter-molecular N-H?S hydrogen bond has also been established, based on freely refined H-atom positions. Inter-molecular C-H?? inter-actions further stabilize the crystal structure.

SUBMITTER: Goh JH 

PROVIDER: S-EPMC2979978 | biostudies-literature | 2010

REPOSITORIES: biostudies-literature