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Dichlorido(1,10-phenanthroline-?N,N')palladium(II).

ABSTRACT: In the title complex, [PdCl(2)(C(12)H(8)N(2))], the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar mol-ecules, with a maximum deviation of 0.120?(3)?Å from the least-squares plane, are stacked in columns along the c axis with a Pd?Pd distance of 4.8340?(9)?Å. In the column, ?-? inter-actions between adjacent six-membered rings are present, the shortest centroid-centroid distance being 3.680?(4)?Å. A weak C-H?Cl inter-action is observed between the columns.

SUBMITTER: Ha K 

PROVIDER: S-EPMC2980155 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Dichlorido(1,10-phenanthroline-κN,N')palladium(II).

Ha Kwang K  

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

In the title complex, [PdCl(2)(C(12)H(8)N(2))], the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar mol-ecules, with a maximum deviation of 0.120 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pd⋯Pd distance of 4.8340 (9) Å. In the column, π-π inter-actions between adjacent six-membered rings are present, the shortest centroid-ce  ...[more]

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