Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dichlorido(1,10-phenanthroline-?N,N')palladium(II).

ABSTRACT: In the title complex, [PdCl(2)(C(12)H(8)N(2))], the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar mol-ecules, with a maximum deviation of 0.120?(3)?Å from the least-squares plane, are stacked in columns along the c axis with a Pd?Pd distance of 4.8340?(9)?Å. In the column, ?-? inter-actions between adjacent six-membered rings are present, the shortest centroid-centroid distance being 3.680?(4)?Å. A weak C-H?Cl inter-action is observed between the columns.

SUBMITTER: Ha K

PROVIDER: S-EPMC2980155 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dichlorido(1,10-phenanthroline-κN,N')palladium(II).

Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

In the title complex, [PdCl(2)(C(12)H(8)N(2))], the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two chloride ions. The nearly planar mol-ecules, with a maximum deviation of 0.120 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pd⋯Pd distance of 4.8340 (9) Å. In the column, π-π inter-actions between adjacent six-membered rings are present, the shortest centroid-ce ...[more]

PMID: 21579936

Similar Datasets

Dichlorido(2,9-dimethyl-1,10-phenanthroline)manganese(II) hemihydrate.

Project description:In the title compound, [MnCl(2)(C(14)H(12)N(2))]·0.5H(2)O, all of the non-H atoms apart from the Cl atom lie on a mirror plane and the methyl H atoms are disordered over two sites of equal occupancy about the mirror plane. The Mn(II) ion is coordinated in a distorted tetra-hedral environment by two N atoms of the phenanthroline ligand and two chloride ions. A half-occupancy solvent water mol-ecule lies on a mirror plane and close to an inversion center.

| S-EPMC2971941 | biostudies-literature

Dichlorido(2,9-dimethyl-1,10-phenanthroline-?N,N')copper(II).

Project description:In the title compound, [CuCl(2)(C(14)H(12)N(2))], the complex molecule has m symmetry, with the mirror plane oriented parallel to the planar molecule and the ligated Cu(II) atom. The metal centre has a distorted tetra-hedral coordination formed by two N atoms from one 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. There is inter-molecular ?-? stacking between adjacent 2,9-dimethyl-1,10-phenanthroline ligands, with a centroid-centroid distance of 3.733?(2)Å.

| S-EPMC2970365 | biostudies-literature

Dichlorido(2,9-dimethyl-1,10-phenanthroline-κN,N')cobalt(II).

Project description:In the title compound, [CoCl(2)(C(14)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. The Co atom and the phenanthroline unit are located on a mirror plane. The methyl H atoms are disordered about the mirror plane and areeach half-occupied. In the crystal structure, π-π inter-actions between the pyridine and benzene rings and between the pyridine rings [centroid-centroid distances = 3.8821 (9) and 3.9502 (10) Å, respectively] stabilize the structure.

| S-EPMC2983147 | biostudies-literature

Dibromido(1,10-phenanthroline-?N,N')palladium(II).

Project description:In the title complex, [PdBr(2)(C(12)H(8)N(2))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two bromide ions. The complex displays numerous inter-molecular ?-? inter-actions between adjacent six-membered rings, the shortest centroid-centroid distance being 3.680?(4)?Å. The nearly planar [maximum deviation 0.143?(2)?Å] mol-ecules stack in columns parallel to (101) with a Pd?Pd distance of 4.8466?(9)?Å.

| S-EPMC2980023 | biostudies-literature

Dichlorido(2,9-dimethyl-1,10-phenanthroline-?(2)N,N')mercury(II).

Project description:The title compound, [HgCl(2)(C(14)H(12)N(2))], consists of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand chelating the Hg(II) ion and two chloride ligands coordinating to the Hg(II) ion, forming a distorted tetra-hedral environment. The dmphen ligand is nearly planar (r.m.s. deviation = 0.0225?Å). The dihedral angle between the normal to the plane defined by the Hg(II) atom and the two Cl atoms and the normal to the plane of the dmphen ring is 81.8?(1)°.

| S-EPMC3569203 | biostudies-literature

Dichlorido(2,9-dieth-oxy-1,10-phenanthroline-?N,N')zinc(II).

Project description:All non-H atoms except for the Cl atoms lie on a mirror plane in the title complex, [ZnCl(2)(C(16)H(16)N(2)O(2))]. The Zn(II) ion is coordinated by two N atoms from a bis-chelating 2,9-dieth-oxy-1,10-phenanthroline ligand and two symmetry-related Cl atoms in a distorted tetra-hedral environment. The two Zn-N bond lengths are significantly different from each other and the N-Zn-N angle is acute. In the crystal structure, there are weak but significant ?-? stacking inter-actions between phenanthroline rings, with a centroid-centroid distance of 3.764?(1)?Å.

| S-EPMC2977366 | biostudies-literature

Dichlorido(2,9-dimeth-oxy-1,10-phenanthroline-?N,N')zinc(II).

Project description:In the crystal structure of the title compound, [ZnCl(2)(C(14)H(12)N(2)O(2))], the Zn(II) center is four-coordinated by two N atoms from one 2,9-dimeth-oxy-1,10-phenanthroline ligand and two Cl atoms. The coordination geometry is distorted tetra-hedral, as the Zn-N bond distances are shorter than the Zn-Cl distances, and the Cl-Zn-N and Cl-Zn-Cl bond angles are much larger than the N-Zn-N angle. For the ligand, the O and C atoms of the meth-oxy groups are almost in the plane defined by the phenanthroline ring. The two O atoms deviate from the phenanthroline mean plane by 0.076?(2) and 0.084?(2)?Å, and the two methyl C atoms deviate from the phenanthroline mean plane by 0.035?(3) and 0.361?(3)?Å. There are medium ?-? stacking interactions between two parallel phenanthroline rings with a centroid-centroid distance of 3.7860?(2)?Å and a dihedral angle between the plane defined by the two parallel phenanthroline rings of 1.13?(5)°.

| S-EPMC2977442 | biostudies-literature

Dichlorido(2-meth-oxy-1,10-phenanthroline-?N,N')zinc(II).

Project description:There are two molecules of the title complex, [ZnCl(2)(C(13)H(10)N(2)O)], in the asymmetric unit. Each Zn atom assumes a distorted tetra-hedral ZnN(2)Cl(2) coordination geometry. There are weak ?-? stacking inter-actions between adjacent 1,10-phenanthroline rings [centroid-centroid distances = 3.6356?(18) and 3.6353?(18)?Å].

| S-EPMC2961575 | biostudies-literature

Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-?N,N')mercury(II) acetonitrile hemisolvate.

Project description:The asymmetric unit of the title compound, [HgCl(2)(C(26)H(20)N(2))]·0.5CH(3)CN, contains two crystallographic-ally independent [HgCl(2)(C(26)H(20)N(2))] mol-ecules and one acetonitrile solvent mol-ecule. The Hg(II) atoms are four-coordin-ated in distorted tetra-hedral configurations by two N atoms from 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligands and two Cl atoms. The ligand ring systems are not planar. The phenyl rings are oriented at dihedral angles of 74.61?(3) and 66.00?(3)° in the two molecules. In the crystal structure, ?-? contacts between phenanthroline rings [centroid-centroid distances = 3.809?(1), 3.686?(1), 3.986?(1), 3.877?(1), 3.697?(1), 3.789?(1), 3.745?(1), 3.797?(1) and 3.638?(1)?Å] may stabilize the structure.

| S-EPMC2977193 | biostudies-literature

Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-?N,N')cobalt(II) dichloro-methane hemisolvate.

Project description:The title compound, [CoCl(2)(C(21)H(17)ClN(2))]·0.5CH(2)Cl(2), crystallizes from dichloro-methane as a 2:1 solvate [CoCl(2)L](2)·CH(2)Cl(2) (L is 2-chloro-9-mesityl-1,10-phenanthroline). There are two independent CoCl(2)L mol-ecules in the asymmetric unit and both mol-ecules have similar conformations. They are connected by a weak C-H?? inter-action involving the mesityl ring. The cobalt center is four-coordinated by the two N-atom donors of the bidentate ligand and two chloride ions in a distorted tetra-hedral geometry. The packing of the mol-ecules is stabilized by weak slipped ?-? stacking inter-actions between symmetry-related phenanthroline groups.

| S-EPMC2961318 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data