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Bis[2-amino-6-methyl-pyrimidin-4(1H)-one-?N,O]dichloridocadmium(II).


ABSTRACT: In the title compound, [CdCl(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is six-coordinated by two heterocyclic N atoms [Cd-N = 2.261?(2) and 2.286?(2)?Å] and two O atoms [Cd-O = 2.624?(2) and 2.692?(2)?Å] from two bidentate chelate 2-amino-6-methyl-pyrimidin-4(1H)-one ligands and two chloride ions [Cd-Cl = 2.4674?(6) and 2.4893?(7)?Å]. The crystal packing is characterized by an open-framework architecture with the crystal packing stabilized by inter-molecular N-H?Cl and N-H?O hydrogen bonds.

SUBMITTER: Kaabi K 

PROVIDER: S-EPMC2983177 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Bis[2-amino-6-methyl-pyrimidin-4(1H)-one-κN,O]dichloridocadmium(II).

Kaabi Kamel K   El Glaoui Meher M   Pereira Silva P S PS   Ramos Silva M M   Ben Nasr Cherif C  

Acta crystallographica. Section E, Structure reports online 20100908 Pt 10


In the title compound, [CdCl(2)(C(5)H(7)N(3)O)(2)], the Cd(II) atom is six-coordinated by two heterocyclic N atoms [Cd-N = 2.261 (2) and 2.286 (2) Å] and two O atoms [Cd-O = 2.624 (2) and 2.692 (2) Å] from two bidentate chelate 2-amino-6-methyl-pyrimidin-4(1H)-one ligands and two chloride ions [Cd-Cl = 2.4674 (6) and 2.4893 (7) Å]. The crystal packing is characterized by an open-framework architecture with the crystal packing stabilized by inter-molecular N-H⋯Cl and N-H⋯O hydrogen bonds. ...[more]

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