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Hexakis(acetonitrile-?N)ruthenium(II) bis-(hexa-bromo-carbadodeca-borate) aceto-nitrile solvate.

ABSTRACT: The title compound, [Ru(NCCH(3))(6)](CH(6)B(11)Br(6))(2)·CH(3)CN, consists of the 'naked' ruthenium(II) cation surrounded by six acetonitrile mol-ecules, each coordinated via the nitro-gen atoms in a linear or nearly-linear fashion in a typical octa-hedral over-all arrangement. The cation is balanced by the two hexa-bromo-carborane cage anionic fragments [CB(11)H(6)Br(6)]. Weak C-H?Br and B-H?Br inter-actions link neighboring anions.

SUBMITTER: Masland J

PROVIDER: S-EPMC2983605 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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Hexakis(acetonitrile-κN)ruthenium(II) bis-(hexa-bromo-carbadodeca-borate) aceto-nitrile solvate.

Masland Joshua J Diaz Jason J Eady Shawn S Lobkovsky Emil E Larsen Anna A

Acta crystallographica. Section E, Structure reports online 20100224 Pt 3

The title compound, [Ru(NCCH(3))(6)](CH(6)B(11)Br(6))(2)·CH(3)CN, consists of the 'naked' ruthenium(II) cation surrounded by six acetonitrile mol-ecules, each coordinated via the nitro-gen atoms in a linear or nearly-linear fashion in a typical octa-hedral over-all arrangement. The cation is balanced by the two hexa-bromo-carborane cage anionic fragments [CB(11)H(6)Br(6)]. Weak C-H⋯Br and B-H⋯Br inter-actions link neighboring anions. ...[more]

PMID: 21580262

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