Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(Aceto-nitrile-?N)iodidobis(tri-phenylphosphane-?P)copper(I).

ABSTRACT: In the mononuclear title complex, [CuI(CH3CN)(C18H15P)2], the Cu(I) ion is in a distorted tetra-hedral geometry, coordinated by two P atoms of two tri-phenyl-phosphane ligands, one N atom of an aceto-nitrile ligand and one iodide anion. The aceto-nitrile ligand is disordered over two sets of sites in a 0.629?(15): 0.371?(15) ratio. In the crystal, weak C-H?I hydrogen bonds link the mol-ecules, forming a chain along [100].

SUBMITTER: Wattanakanjana Y

PROVIDER: S-EPMC4051102 | biostudies-literature | 2014 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(Aceto-nitrile-κN)iodidobis(tri-phenylphosphane-κP)copper(I).

Wattanakanjana Yupa Y Nimthong Arunpatcha A Mokakul Jedsada J Sukpornsawan Phattarin P

Acta crystallographica. Section E, Structure reports online 20140517 Pt 6

In the mononuclear title complex, [CuI(CH3CN)(C18H15P)2], the Cu(I) ion is in a distorted tetra-hedral geometry, coordinated by two P atoms of two tri-phenyl-phosphane ligands, one N atom of an aceto-nitrile ligand and one iodide anion. The aceto-nitrile ligand is disordered over two sets of sites in a 0.629 (15): 0.371 (15) ratio. In the crystal, weak C-H⋯I hydrogen bonds link the mol-ecules, forming a chain along [100]. ...[more]

PMID: 24940205

Similar Datasets

Tris(aceto-nitrile-?N)dichlorido(tri-phenyl-phosphane-?P)ruthenium(II) aceto-nitrile monosolvate.

Project description:In the title complex, [RuCl2(CH3CN)3(C18H15P)]·CH3CN, the coordination geometry of the Ru(II) atom is distorted octa-hedral, defined by one P atom from a tri-phenyl-phosphane ligand, three N atoms from three aceto-nitrile ligands and two Cl atoms. The three acetronitile ligands linearly bind to the Ru(II) atom, with Ru-N-C angles of 172.6?(2), 179.9?(2) and 171.4?(2)°.

| S-EPMC3684898 | biostudies-literature

Tetra-kis(aceto-nitrile)copper(I) hydrogen oxalate-oxalic acid-aceto-nitrile (1/0.5/0.5).

Project description:In the title compound, [Cu(CH3CN)4](C2HO4)·0.5C2H2O4·0.5CH3CN, the Cu(I) ion is coordinated by the N atoms of four aceto-nitrile ligands in a slightly distorted tetra-hedral environment. The oxalic acid mol-ecule lies across an inversion center. The aceto-nitrile solvent mol-ecule is disordered across an inversion center and was refined with half occupancy. In the crystal, the hydrogen oxalate anions and oxalic acid mol-ecules are linked via O-H?O hydrogen bonds, forming chains along [010].

| S-EPMC3790353 | biostudies-literature

Octa-?3-selenido-penta-kis-(tri-ethyl-phos-phane-?P)(tri-methyl-aceto-nitrile-?N)-octa-hedro-hexa-rhenium(III) bis-(hexa-fluorido-anti-monate) tri-methyl-aceto-nitrile monosolvate.

Project description:The crystal structure of the title compound, [Re6Se8{NCC(CH3)3}(Et3P)5](SbF6)2·NCC(CH3)3, contains a face-capped octa-hedral [Re6(?3-Se)8](2+) cluster core. The pseudo-centrosymmetric [Re6Se8](2+) cluster core is bonded through the Re atoms to five tri-ethyl-phosphane ligands and one tri-methyl-aceto-nitrile ligand. No significant interactions are observed between the cationic cluster, the SbF6 (-) anions and the trimethylacetonitrile solvent molecule.

| S-EPMC4120548 | biostudies-literature

Crystal structure of di-?-iodido-bis-[bis(aceto-nitrile-?N)copper(I)].

Project description:The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu?Cu distance = 2.7482?(11)?Å], the Cu(I) atoms of which are further coordinated by four mol-ecules of aceto-nitrile. The Cu(I) atom has an overall distorted tetra-hedral coordination environment evidenced by L-Cu-L angles (L = N or I) ranging from 100.47?(10) to 117.06?(2)°. The coordination geometries of the aceto-nitrile ligands deviate slightly from linearity as shown by Cu-N-C angles of 167.0?(2) and 172.7?(2)°. In the crystal, there are no significant hydrogen-bonding inter-actions present, so the crystal packing seems to be formed predominantly by van der Waals forces.

| S-EPMC4645014 | biostudies-literature

Bis(isonicotinamide-κ<i>N</i>)silver(I) tri-fluoro-methane-sulfonate aceto-nitrile disolvate.

Project description:The central AgI atom of the title salt, [Ag(INAM)2](CF3SO3)·2CH3CN, where INAM is isonicotinamide (C6H6N2O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear mol-ecular geometry. The formation of polymeric chains {[Ag(INAM)2]+} n , held together by discrete hydrogen bonds through the amide group of the INAM ligand leaves voids for non-coordinating aceto-nitrile mol-ecules that inter-act the silver metal center via regium bonds.

| S-EPMC9462304 | biostudies-literature

{Dimeth-yl [(phenyl-sulfon-yl)amido-]phosphato-?(2) O,O'}bis-(tri-phenylphosphane-?P)copper(I).

Project description:In the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the Cu(I) ion is coordinated by two tri-phenyl-phosphane mol-ecules and two O atoms of the chelating dimeth-yl(phenyl-sulfon-yl)amido-phosphate anion, generating a squashed CuO2P2 tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost coplanar (r.m.s. deviation = 0.024?Å), with the N and S atoms displaced in the same direction, by 0.708?(5) and 0.429?(2)?Å, respectively.

| S-EPMC4051010 | biostudies-literature

Bis{2-[(Tri-phenyl-meth-yl)amino]-phen-yl} diselenide aceto-nitrile monosolvate.

Project description:The mol-ecular structure of the title compound, C50H40N2Se2·C2H3N, shows a syn conformation of the benzene rings bound to the Se atoms, with an Se-Se bond length of 2.3529?(6)?Å and a C-Se-Se-C torsion angle of 93.53?(14)°. The two Se-bonded aromatic ring planes make a dihedral angle of 18.42?(16)°. Intra-molecular N-H?Se hydrogen bonds are noted. Inter-molecular C-H?Se inter-actions give rise to supra-molecular chains extended along [100]. One severely disordered aceto-nitrile solvent mol-ecule per asymmetric unit was treated with SQUEEZE in PLATON [Spek (2009 ?). Acta Cryst. D65, 148-155]; the crystal data take the presence of this mol-ecule into account.

| S-EPMC4011201 | biostudies-other

Serendipitous preparation of fac-(aceto-nitrile-κN)tri-chlorido-[(1,2,5,6-η)-cyclo-octa-1,5-diene]iridium(III).

Project description:A reaction between [(COD)IrCl]2 (COD is cyclo-octa-1,5-diene), HCl and indene failed to provide the hoped for chlorido-indenyliridium dimer, but instead produced the title compound, [IrCl3(CH3CN)(C8H12)], which is an octa-hedral complex of iridium(III) with a chelating cyclo-octa-1,5-diene ligand, three chloride ligands in a fac arrangement, and one aceto-nitrile ligand. Attempts to devise a rational synthesis for the title compound were unsuccessful.

| S-EPMC4438853 | biostudies-literature

trans-Tetra-chloridobis(diphenyl-aceto-nitrile)platinum(IV).

Project description:In the title compound, [PtCl(4)(C(14)H(11)N)(2)], the Pt atom lies on an inversion center and has a distorted octa-hedral environment. The main geometric parameters are Pt-N = 1.960 (5) Å, and Pt-Cl = 2.3177 (12) and 2.3196 (12) Å. The N C bond is a typical triple bond [1.137 (7) Å]. The Pt-N C-C unit is almost linear, with Pt-N-C and N-C-C angles of 174.6 (4) and 177.1 (6)°, respectively.

| S-EPMC2969749 | biostudies-literature

trans-Tetra-iodidobis(tri-p-tolyl-phosphine oxide-?O)tin(IV).

Project description:The centrosymmetric title compound, [SnI(4)(C(21)H(21)OP)(2)], is a monomeric complex that displays a nearly octa-hedral coordination of tin(IV), with an Sn-O bond distance of 2.159?(2)?Å and an average Sn-I bond distance of 2.79?(3)?Å.

| S-EPMC2960702 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data