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Bis(tetra-phenyl-phospho-nium) tetra-iodidomanganate(II) acetone monosolvate.

ABSTRACT: The title compound, (C(24)H(20)P)(2)[MnI(4)]·(CH(3))(2)CO, prepared from the reaction of manganese powder, iodine and tetra-phenyl-phospho-nium iodide in acetone shows a tetra-hedral complex anion [Mn-I = 2.6868?(5)-2.7281?(4)?Å and I-Mn-I = 104.011?(13)-116.164?(15)°], two tetra-phenyl-phospho-nium cations and one mol-ecule of acetone.

SUBMITTER: Jalilian E

PROVIDER: S-EPMC2983621 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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Bis(tetra-phenyl-phospho-nium) tetra-iodidomanganate(II) acetone monosolvate.

Jalilian Ehsan E Lidin Sven S

Acta crystallographica. Section E, Structure reports online 20100227 Pt 3

The title compound, (C(24)H(20)P)(2)[MnI(4)]·(CH(3))(2)CO, prepared from the reaction of manganese powder, iodine and tetra-phenyl-phospho-nium iodide in acetone shows a tetra-hedral complex anion [Mn-I = 2.6868 (5)-2.7281 (4) Å and I-Mn-I = 104.011 (13)-116.164 (15)°], two tetra-phenyl-phospho-nium cations and one mol-ecule of acetone. ...[more]

PMID: 21580270

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