Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis(tetra-phenyl-phospho-nium) bis-[N-(2,5-dichloro-phenyl-sulfon-yl)dithio-carbimato(2-)-?S,S']platinate(II).

ABSTRACT: In the title salt, (C(24)H(20)P)(2)[Pt(C(7)H(3)Cl(2)NO(2)S(3))(2)], the Pt(II) ion (site symmetry ) is coordinated by two S,S'-bidentate N-(2,5-dichloro-phenyl-sulfon-yl)dithio-carbimate ligands, resulting in a slightly distorted PtS(4) square-planar geometry. In the crystal, a C-H?O inter-action is observed, as well as electrostatic attraction between the oppositely charged ions.

SUBMITTER: Guilardi S

PROVIDER: S-EPMC2983738 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis(tetra-phenyl-phospho-nium) bis-[N-(2,5-dichloro-phenyl-sulfon-yl)dithio-carbimato(2-)-κS,S']platinate(II).

Guilardi S S Flauzino Neto Wilson P WP Vieira Lucas C C LC Amin Raquel S RS Oliveira Marcelo R L MR

Acta crystallographica. Section E, Structure reports online 20100203 Pt 3

In the title salt, (C(24)H(20)P)(2)[Pt(C(7)H(3)Cl(2)NO(2)S(3))(2)], the Pt(II) ion (site symmetry ) is coordinated by two S,S'-bidentate N-(2,5-dichloro-phenyl-sulfon-yl)dithio-carbimate ligands, resulting in a slightly distorted PtS(4) square-planar geometry. In the crystal, a C-H⋯O inter-action is observed, as well as electrostatic attraction between the oppositely charged ions. ...[more]

PMID: 21580206

Similar Datasets

Bis(tetra-phenyl-phospho-nium) bis-[N-(phenyl-sulfon-yl)dithio-carbimato-?S,S']platinate(II) monohydrate.

Project description:The asymmetric unit of the title compound, (C(24)H(20)P)(2)[Pt(C(7)H(5)NO(2)S(3))(2)]·H(2)O, consists of two tetra-phenyl-phospho-nium cations, two half bis-[N-(phenyl-sulfon-yl)dithio-carbim-ato]platinate(II) dianions and one water mol-ecule. The anions are completed by crystallographic inversion symmetry associated with the central Pt(II) ion. The Pt(II) ion is doubly S,S'-chelated by two symmetry-related phenyl-sulfonyl-dithio-carbimate ligands, forming a slightly distorted square-planar configuration. Besides the electrostatic attraction between oppositely charged ions in the crystal packing, intra-molecular C-H?O and several inter-molecular C-H?O, C-H?N and O-H?O hydrogen-bonding inter-actions between the cations, anions and water mol-ecules are observed.

| S-EPMC3007205 | biostudies-literature

Bis(tetra-phenyl-phospho-nium) bis-[N-(octyl-sulfon-yl)dithio-carbimato(2-)-κS,S']-nickelate(II).

Project description:The Ni atom in the title complex, (C(24)H(20)P)(2)[Ni(C(9)H(17)NO(2)S(3))(2)], lies on a twofold axis within a square-planar geometry defined by four S atoms derived from two dithio-carbimate dianions, each forming a four-membered chelate ring. A small distortion, described by a deviation of the Ni(II) atom by 0.083 (1) Å from the plane through the four S atoms, and also by the torsion angles about the Ni-S bonds, implies a folded conformation for the chelate ring.

| S-EPMC2915091 | biostudies-literature

Bis(tetra-phenyl-phospho-nium) bis-[N-(trifluoro-methyl-sulfon-yl)dithio-carbimato(2-)-κS,S']zincate(II).

Project description:The title salt, (C(24)H(20)P)(2)[Zn(C(2)F(3)NO(2)S(3))(2)], consists of a complex dianion and two tetra-phenyl-phospho-nium cations. The Zn(II) ion displays a distorted tetra-hedral coordination environment with four S atoms from two S,S'-chelated N-(trifluoro-methyl-sulfonyl-)dithio-carbimate anions. In the crystal, besides the ionic inter-action of the oppositely charged ions, inter-molecular C-H⋯O inter-actions between cations and anions are observed. One of the cations inter-acts with an inversion-related equivalent by π-π stacking between phenyl rings, with a centroid-centroid distance of 3.932 (4) Å.

| S-EPMC3254306 | biostudies-literature

Bis(tetra-phenyl-phospho-nium) tetra-sulfido-tungstate(VI).

Project description:The crystal structure of the title compound, (C(24)H(20)P)(2)[WS(4)], which was prepared under hydro-thermal conditions, contains tetra-phenyl-phospho-nium cations linked by supra-molecular inter-actions into chains running along the [110] and [10] directions. The [WS(4)](2-)anions, which lie on twofold axes, are located in the cavities created between the cation chains.

| S-EPMC2960978 | biostudies-literature

Bis(tetra-phenyl-phospho-nium) tetra-chlorido-cobaltate(II).

Project description:The title compound, (C24H20P)2[CoCl4], was prepared under hydro-thermal conditions. In the crystal, the tetra-phenyl-phospho-nium cations are linked by pairs of weak C-H⋯π inter-actions into supra-molecular dimers; the Co(II) cations lie on twofold rotation axes and the tetra-hedral [CoCl4](2-) anions are linked with the tetra-phenyl-phospho-nium cations via weak C-H⋯Cl hydrogen bonds.

| S-EPMC4051096 | biostudies-literature

Bis(tetra-phenyl-phospho-nium) tris-[N-(methyl-sulfon-yl)dithio-carbimato(2-)-?S,S']stannate(IV).

Project description:In the title complex, (C(24)H(20)P)(2)[Sn(C(2)H(3)NO(2)S(3))(3)], the Sn(IV) atom is coordinated by three N-(methyl-sulfon-yl)dithio-carbimate bidentate ligands through the anionic S atoms in a slightly distorted octa-hedral coordination geometry. There is one half-mol-ecule in the asymmetric unit; the complex is located on a crystallographic twofold rotation axis passing through the cation and bis-ecting one of the (non-symmetric) ligands, which appears thus disordered over two sites of equal occupancy. In the crystal structure, weak inter-molecular C-H?O and C-H?S inter-actions contribute to the packing stabilization.

| S-EPMC2970435 | biostudies-other

Bis(tetra-phenyl-phospho-nium) tetra-iodidomanganate(II) acetone monosolvate.

Project description:The title compound, (C(24)H(20)P)(2)[MnI(4)]·(CH(3))(2)CO, prepared from the reaction of manganese powder, iodine and tetra-phenyl-phospho-nium iodide in acetone shows a tetra-hedral complex anion [Mn-I = 2.6868?(5)-2.7281?(4)?Å and I-Mn-I = 104.011?(13)-116.164?(15)°], two tetra-phenyl-phospho-nium cations and one mol-ecule of acetone.

| S-EPMC2983621 | biostudies-literature

[1,4-Phenyl-enebis(methyl-ene)]bis-(tri-phenyl-phospho-nium) bis-(tetra-fluoro-borate).

Project description:The crystal structure of the title salt, C(44)H(38)P(2) (2+)2BF(4) (-), consists of discrete dications inter-laced with the BF(4) (-) counter-ions. In each cation, both phospho-nium groups lie on the same side of the plane of the central benzene ring. The tetra-fluoro-borate anions are involved in intensive thermal motion, thus some B-F bond lengths [range 1.329 (6) to 1.391 (6) Å] deviate significantly from their standard values.

| S-EPMC3239032 | biostudies-literature

Bis(tetra-phenyl-phospho-nium) di-μ-iodido-bis[di-iodido-tellurate(II)].

Project description:The structure of the title compound, (C(24)H(20)P)(2)[Te(2)I(6)], is composed of discrete PPh(4) (+) cations and centrosymmetric [Te(2)I(6)](2-) anions. The tellurium(II) atom shows a sligthly distorted square-planar TeI(4) geometry and is coordinated to two bridging and two terminal iodine atoms. The planar [Te(2)I(6)](2-) ions are isolated by the cations and no inter-molecular tellurium-halogen or halogen-halogen inter-actions are present.

| S-EPMC2959816 | biostudies-literature

Tetra-phenyl-phospho-nium hydrogen oxalate.

Project description:In the title compound, C(24)H(20)P(+)·C(2)HO(4) (-), two symmetry-independent ion pairs are present. The cations aggregate into puckered sheets via zigzag infinite chains of sixfold phenyl embraces and parallel fourfold phenyl embraces, while the anions form hydrogen-bonded chains between the sheets of cations. In the two independent oxalate anions, the angles between the normals to the two least-squares carboxyl-ate COO planes are unusually large, viz. 72.5 (1) and 82.1 (1)°.

| S-EPMC2915301 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data