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Bis(tetra-phenyl-phospho-nium) bis-[N-(phenyl-sulfon-yl)dithio-carbimato-?S,S']platinate(II) monohydrate.

ABSTRACT: The asymmetric unit of the title compound, (C(24)H(20)P)(2)[Pt(C(7)H(5)NO(2)S(3))(2)]·H(2)O, consists of two tetra-phenyl-phospho-nium cations, two half bis-[N-(phenyl-sulfon-yl)dithio-carbim-ato]platinate(II) dianions and one water mol-ecule. The anions are completed by crystallographic inversion symmetry associated with the central Pt(II) ion. The Pt(II) ion is doubly S,S'-chelated by two symmetry-related phenyl-sulfonyl-dithio-carbimate ligands, forming a slightly distorted square-planar configuration. Besides the electrostatic attraction between oppositely charged ions in the crystal packing, intra-molecular C-H?O and several inter-molecular C-H?O, C-H?N and O-H?O hydrogen-bonding inter-actions between the cations, anions and water mol-ecules are observed.

SUBMITTER: Silverio HA 

PROVIDER: S-EPMC3007205 | biostudies-literature | 2010

REPOSITORIES: biostudies-literature

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Bis(tetra-phenyl-phospho-nium) bis-[N-(phenyl-sulfon-yl)dithio-carbimato-κS,S']platinate(II) monohydrate.

Silvério H A HA   Guilardi S S   Flauzino Neto Wilson P WP   Amin Raquel S RS   Oliveira Marcelo R L MR  

Acta crystallographica. Section E, Structure reports online 20100721 Pt 8

The asymmetric unit of the title compound, (C(24)H(20)P)(2)[Pt(C(7)H(5)NO(2)S(3))(2)]·H(2)O, consists of two tetra-phenyl-phospho-nium cations, two half bis-[N-(phenyl-sulfon-yl)dithio-carbim-ato]platinate(II) dianions and one water mol-ecule. The anions are completed by crystallographic inversion symmetry associated with the central Pt(II) ion. The Pt(II) ion is doubly S,S'-chelated by two symmetry-related phenyl-sulfonyl-dithio-carbimate ligands, forming a slightly distorted square-planar conf  ...[more]

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