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[(1R)-3-Benzoyl-1,7,7-trimethyl-bicyclo-[2.2.1]heptan-2-onato-?O,O']chlorido(?-p-cymene)ruthenium(II).

ABSTRACT: The asymmetric unit of the title compound, [RuCl(C(10)H(14))(C(17)H(19)O(2))], contains two diastereomers. In both, the Ru(II) ion has a tetra-hedral coordination, formed by two O atoms of the camphor-derived ligand and the p-cymene and Cl ligands. In the crystal structure, weak inter-molecular C-H?Cl inter-actions link the mol-ecules into columns propagated along [010].

SUBMITTER: Harrad MA

PROVIDER: S-EPMC2983648 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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[(1R)-3-Benzoyl-1,7,7-trimethyl-bicyclo-[2.2.1]heptan-2-onato-κO,O']chlorido(η-p-cymene)ruthenium(II).

Harrad Mohamed Anouar MA Valerga Pedro P Puerta M Carmen MC Ali Mustapha Ait MA El Firdoussi Larbi L Karim Abdellah A

Acta crystallographica. Section E, Structure reports online 20100213 Pt 3

The asymmetric unit of the title compound, [RuCl(C(10)H(14))(C(17)H(19)O(2))], contains two diastereomers. In both, the Ru(II) ion has a tetra-hedral coordination, formed by two O atoms of the camphor-derived ligand and the p-cymene and Cl ligands. In the crystal structure, weak inter-molecular C-H⋯Cl inter-actions link the mol-ecules into columns propagated along [010]. ...[more]

PMID: 21580227

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