Ontology highlight
ABSTRACT:
SUBMITTER: Lo KM
PROVIDER: S-EPMC2977628 | biostudies-literature | 2009 Apr
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20090430 Pt 5
The Mn(II) atom in the two independent ion-pairs of the title salt, [Mn(C(2)F(3)O(2))(C(18)H(12)N(6))(H(2)O)(2)]C(2)F(3)O(2), is N,N',N''-chelated by the neutral N-heterocycle and O,O'-chelated by the carboxyl-ate ion, the five atoms involved in chelation comprising a penta-gon around it. The apical sites of the trans-penta-gonal bipyramidal coordination geometry are occupied by two water mol-ecules. The cations and lattice anions are linked by O-H⋯O and O-H⋯N hydrogen bonds into a three-dimensi ...[more]