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Tris(o-chloro-benz-yl)[3-(4-meth-oxybenzoyl)-propionato-?O]tin(IV).

ABSTRACT: The tin atom in the title compound, [Sn(C(7)H(6)Cl)(3)(C(11)H(11)O(4))], exists in a distorted tetra-hedral coordination environment. The carboxyl-ate anion is equally disordered over two positions.

SUBMITTER: Keng TC

PROVIDER: S-EPMC2983718 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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Tris(o-chloro-benz-yl)[3-(4-meth-oxybenzoyl)-propionato-κO]tin(IV).

Keng Thy Chun TC Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100220 Pt 3

The tin atom in the title compound, [Sn(C(7)H(6)Cl)(3)(C(11)H(11)O(4))], exists in a distorted tetra-hedral coordination environment. The carboxyl-ate anion is equally disordered over two positions. ...[more]

PMID: 21580255

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Tris(2-chloro-benz-yl)(1H-1,2,4-triazole-5-thiol-ato-κS)tin(IV)-tris-(2-chloro-benz-yl)(4H-1,2,4-triazole-3-thiol-ato-κS)tin(IV) (1/1).

Project description:Tris(2-chloro-benz-yl)tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C(7)H(6)Cl)(3)(C(2)H(2)N(3)S)]. The asymmetric unit contains two mol-ecules which differ only in the position of the nitro-gen-bound H atom of the triazole ring; one mol-ecule is linked to the other mol-ecule by an N-H⋯N hydrogen bond. In the second mol-ecule, two of the chloro-benzyl units are disordered over two positions in a 0.73 (1):0.27 (1) ratio. The Sn atom in both mol-ecules shows a distorted tetra-hedral SnSC(3) coordination.

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Project description:The Sn atom in the title compound, [Sn(C(7)H(6)Cl)(3)(C(8)H(14)NO(2)S(2))], is coordinated by three chlorobenzyl ligands and one carboxylate O atom of the substituted acetate ligand in a distorted tetra-hedral environment. Three of the C atoms of the n-butyl group are disordered over two sites with equal occupancies.

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Project description:In the title mol-ecule, [Sn(C(7)H(6)Cl)(2)(C(6)H(4)NO(2))(2)(H(2)O)], the O atoms of the two chelating nicotinate groups and the O atom of the coordinated water mol-ecule comprise the penta-gonal plane of the trans-C(2)SnO(5) penta-gonal-bipyramid [C-Sn-C = 178.62?(11) °] surrounding the Sn(IV) atom. In the crystal, adjacent mol-ecules are linked by O-H?N hydrogen bonds, generating a chain running along the body diagonal of the triclinic unit cell.

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Dichloridobis(4-chloro-benz-yl)(4,4'-dimethyl-2,2'-bipyridine-κN,N')tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(12)H(12)N(2))], is coordinated by the bidentate N-heterocycle mol-ecule, two chloro-benzyl anions and two Cl(-) anions in a distorted trans-C(2)SnCl(2)N(2) octa-hedral geometry [C-Sn-C = 178.4 (1)°]. In the mol-ecular structure, the two benzene rings are oriented at a dihedral angle of 39.62 (17)°.

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catena-Poly[[tris-(4-fluoro-benz-yl)tin(IV)]-?-2-[(piperidin-1-yl)carbothio-ylsulfan-yl]acetato-?O:O'].

Project description:Adjacent units of the title polymeric complex, [Sn(C(7)H(6)F)(3)(C(8)H(12)NO(2)S(2))], are bridged by the carboxyl-ate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C(3)SnO(2) trigonal-bipyramidal coordination and is displaced by 0.113?(2)?Å out of the C(3)Sn girdle in the direction of the covalently bonded O atom. The ring is disordered of two positions with an occupancy of 0.631?(4) for the major occupied site.

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