Browse
Submit Data
Databases
API
Help

Dataset Information

32 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Di-?-thio-cyanato-bis-[bis-(tri-p-tolyl-phosphine)silver(I)] 0.35-hydrate.

ABSTRACT: In the binuclear centrosymmetric title compound, [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·0.35H(2)O, a pseudo-polymorph of [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·2CH(3)CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The crystal structure exhibits inter-molecular C-H?? inter-actions.

SUBMITTER: Khumalo NM

PROVIDER: S-EPMC2984055 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Di-μ-thio-cyanato-bis-[bis-(tri-p-tolyl-phosphine)silver(I)] 0.35-hydrate.

Khumalo Nozipho M NM Meijboom Reinout R Muller Alfred A Omondi Bernard B

Acta crystallographica. Section E, Structure reports online 20100327 Pt 4

In the binuclear centrosymmetric title compound, [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·0.35H(2)O, a pseudo-polymorph of [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·2CH(3)CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The crystal structure exhibits inter-molecular C-H⋯π inter-actions. ...[more]

PMID: 21580539

Similar Datasets

Tri-p-tolyl-phosphine.

Project description:In the title compound C(21)H(21)P, the P atom is situated on a crystallographic threefold rotatory-inversion axis, resulting in threefold rotation symmetry of the title compound. The dihedral angles between the symmetry-related benzene rings are 87.40?(18)°.

| S-EPMC2960611 | biostudies-literature

Di-?-thio-cyanato-bis-{[1,2-bis-(diiso-propyl-phosphan-yl)-1,2-dicarba-closo-dodeca-borane]silver(I)}.

Project description:The title compound, [Ag(2)(NCS)(2)(C(14)H(38)B(10)P(2))(2)], was synthesized by the reaction of 1,2-bis-(diiso-propyl-phos-phan-yl)-1,2-dicarba-closo-dodeca-borane with AgSCN. The diisopropyl-phosphanyl-closo-carborane ligand is coordinated in a bidentate manner to the Ag(I) atom through the two P atoms. The coordination of the Ag(I) atom is distorted tetra-hedral, in which two vertices are formed by the P atoms of the chelating diphosphine ligand, and the other two are occupied by the S and N atoms of the two bridging thio-cyanate anions, leading to a centrosymmetric binuclear complex. The distance between the two C atoms in the carborane skeleton is 1.851?(6)?Å.

| S-EPMC3050408 | biostudies-literature

Poly[bis(?(3)-thio-cyanato-?N:S:S')(?(2)-thio-cyanato-?N:S)(4'-p-tolyl-2,2':6',2''-terpyridine-?N,N',N'')cadmium(II)silver(I)].

Project description:The title compound, [AgCd(NCS)(3)(C(22)H(17)N(3))](n), is a hetero-atom ribbon coordination polymer. The central Cd atom is chelated by the 4'-p-tolyl-2,2':6',2''-terpyridine ligand and is coordinated by the N atoms of three thio-cyanate ions in an octa-hedral geometry whereas the Ag atom is coordinated by the four S atoms of four thio-cyanate ions in a distorted tetra-hedral geometry. Of the three thio-cyanate ions, one functions in a ?(2)-bridging mode and two in a ?(3)-bridging mode. The ribbon coordination polymer propagates along the a-axis.

| S-EPMC2983338 | biostudies-literature

Di-?-thio-cyanato-?N:S;?S:N-bis-[bis-(2-methyl-1H-benzimidazole-?N)(thio-cyanato-?N)cadmium(II)].

Project description:The title compound, [Cd(2)(NCS)(4)(C(8)H(8)N(2))(4)], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thio-cyanate N:S-bridges. Two 2-methyl-benzimidazole N-atom donors and one terminal thio-cyanate N atom complete a highly distorted square-pyramidal geometry around the Cd atom. In the crystal structure, two N-H?S hydrogen-bonding inter-actions occur, resulting in a three-dimensional polymeric structure. The apical 2-methyl-benzimidazole ring and its symmetry-related counterpart are arranged in an anti-parallel manner with a centroid-centroid separation of 3.6050?(14)?Å, indicative of a ?-? inter-action.

| S-EPMC3009005 | biostudies-literature

[(Z)-N-Isopropyl-O-methyl-thio-carbamato-?S](tri-p-tolyl-phosphine-?P)gold(I).

Project description:In the title compound, [Au(C(5)H(10)NOS)(C(21)H(21)P)], two independent mol-ecules comprise the asymmetric unit, and these are connected by an aurophilic inter-action [Au?Au = 3.1351?(3)?Å]. Each Au(I) atom is linearly coordinated within a S,P-donor set with the distortion from ideal linear geometry [S-Au-P = 175.31?(5) and 176.45?(5)°] ascribed to an intra-molecular Au?O contact in each case [2.974?(4) and 3.027?(4)?Å].

| S-EPMC2972070 | biostudies-literature

Di-aqua-bis-(nicotinamide-?N (1))bis-(thio-cyanato-?N)nickel(II).

Project description:In the title complex, [Ni(NCS)2(C6H6N2O)2(H2O)2], the Ni(II) ion is located on an inversion center and is coordinated in a distorted octa-hedral environment by two N atoms from two nicotinamide ligands and two water mol-ecules in the equatorial plane, and two N atoms from two thio-cyanate anions in the axial positions, all acting as monodentate ligands. In the crystal, weak N-H?S hydrogen bonds between the amino groups and the thio-cyanate anions form an R 4 (2)(8) motif. The complex mol-ecules are linked by O-H?O, O-H?S, and N-H?S hydrogen bonds into a three-dimensional supra-molecular structure. Weak ?-? inter-actions between the pyridine rings is also found [centroid-centroid distance = 3.8578?(14)?Å].

| S-EPMC4011277 | biostudies-literature

Di-?-hydroxido-bis-[dimeth-yl(thio-cyanato-?N)tin(IV)].

Project description:The Sn(IV) atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thio-cyanate anion are in the apical >positions. The dinuclear species are linked through O-H?S and C-H? S hydrogen-bonding inter-actions into a three-dimensional network.

| S-EPMC3588706 | biostudies-literature

catena-Poly[(E)-4,4'-(ethene-1,2-di-yl)dipyridinium [[bis-(thio-cyanato-?N)ferrate(II)]-di-?-thio-cyanato-?N:S;?S:N]].

Project description:In the title compound, {(C(12)H(12)N(2))[Fe(NCS)(4)]}(n), each Fe(II) cation is coordinated by four N-bonded and two S-bonded thio-cyanate anions in an octa-hedral coordination mode. The asymmetric unit consists of one Fe(II) cation, located on a center of inversion, as well as one protonated (E)-4,4'-(ethene-1,2-di-yl)dipyridinium dication and two thio-cyanate anions in general positions. The crystal structure consists of Fe-(NCS)(2)-Fe chains extending along the a axis, in which two further thio-cyanate anions are only terminally bonded via nitro-gen. Non-coordinating (E)-4,4'-(ethene-1,2-di-yl)dipyrid-inium cations are found between the chains.

| S-EPMC2983361 | biostudies-literature

Bis(di-2-pyridyl-amine-?N,N')bis-(thio-cyanato-?N)nickel(II).

Project description:The mononuclear neutral title complex, [Ni(NCS)(2)(C(10)H(9)N(3))(2)], shows a cis-octa-hedral geometry around the Ni(II) ion, formed by two chelating di-2-pyridyl-amine (Hdpa) ligands and two thio-cyanate anions. Both amine H atoms are involved in N-H?S hydrogen bonding, resulting in the formation of layers of inter-linked mol-ecules parallel to the ab plane, which are further held together by weak ?-? inter-actions between adjacent complexes, involving one ring of each dipyridyl-amine unit [centroid-centroid distance = 3.777?(4)?Å], forming a three-dimensional assembly.

| S-EPMC3238757 | biostudies-literature

catena-Poly[[bis-(thio-cyanato-?N)cobalt(II)]-di-?-thio-urea-?(4)S:S].

Project description:In the title polymeric complex, [Co(NCS)(2){SC(NH(2))(2)}(2)](n), the asymmetric unit comprises a Co(II) ion, which is situated on an inversion centre, an N-bound thio-cyanate anion and a ?(2)-bridging thio-urea mol-ecule. The Co(II) atom is coordinated in a distorted octa-hedral fashion within an N(2)S(4) donor set. The bridging thio-urea ligands link Co(II) ions into a polymeric chain extending along [100]. The mol-ecular conformation is stabilized by intra-molecular N-H?N hydrogen bonds, which generate S(6) ring motifs. The crystal packing is stabilized by N-H?S inter-actions, which connect the chains into a three-dimensional architecture.

| S-EPMC3414167 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data