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{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N'',N'''}(thio-cyanato-?N)zinc(II) perchlorate.

ABSTRACT: In the title compound, [Zn(NCS)(C(16)H(18)N(4))]ClO(4), the Zn(II) atom is five-coordinated by four N atoms of the Schiff base ligand N,N'-bis-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine in the basal plane, and by the N atom of a thio-cyanate ligand at the apical position, forming a distorted square-pyramidal geometry. The r.m.s. deviation from a plane through the four N atoms of the Schiff base is 0.015?(3)?Å, and the deviation of the Ni atom from that plane is 0.591?(2)?Å. Bond lengths are comparable with those observed in similar zinc(II) complexes with Schiff bases. The two methyl-ene C atoms of the ethane-1,2-diamine bridge of the Schiff base ligand are disordered over two sites with occupancies of 0.587?(3) and 0.413?(3).

SUBMITTER: Wang FM

PROVIDER: S-EPMC3006726 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N'',N'''}(thio-cyanato-κN)zinc(II) perchlorate.

Wang Fu-Ming FM

Acta crystallographica. Section E, Structure reports online 20100616 Pt 7

In the title compound, [Zn(NCS)(C(16)H(18)N(4))]ClO(4), the Zn(II) atom is five-coordinated by four N atoms of the Schiff base ligand N,N'-bis-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine in the basal plane, and by the N atom of a thio-cyanate ligand at the apical position, forming a distorted square-pyramidal geometry. The r.m.s. deviation from a plane through the four N atoms of the Schiff base is 0.015 (3) Å, and the deviation of the Ni atom from that plane is 0.591 (2) Å. Bond lengths are c ...[more]

PMID: 21587706

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