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{N-Methyl-N'-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N''}-bis(thio-cyanato-?N)zinc(II).

ABSTRACT: In the title compound, [Zn(NCS)(2)(C(10)H(15)N(3))], the Zn atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two N atoms from two thio-cyanate anions, forming a distorted ZnN(5) trigonal-bipyramidal coordination geometry for the metal ion. The side chain of the ligand is disordered over two sets of sites in a 0.655?(12):0.345?(12) ratio. In the crystal, mol-ecules are linked by N-H?S hydrogen bonds, generating [100] chains.

SUBMITTER: Li XW

PROVIDER: S-EPMC3151752 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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{N-Methyl-N'-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}-bis(thio-cyanato-κN)zinc(II).

Li Xian-Wen XW

Acta crystallographica. Section E, Structure reports online 20110604 Pt 7

In the title compound, [Zn(NCS)(2)(C(10)H(15)N(3))], the Zn atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two N atoms from two thio-cyanate anions, forming a distorted ZnN(5) trigonal-bipyramidal coordination geometry for the metal ion. The side chain of the ligand is disordered over two sets of sites in a 0.655 (12):0.345 (12) ratio. In the crystal, mol-ecules are linked by N-H⋯S hydrogen bonds, generating [100] chains. ...[more]

PMID: 21836839

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