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Chlorido(2,3,7,8,12,13,17,18-octa-ethyl-porphyrinato)iron(III) dichloro-methane sesquisolvate.

ABSTRACT: The title mol-ecule, [Fe(C(36)H(44)N(4))Cl]·1.5CH(2)Cl(2), is a high-spin square-pyramidal iron(III) porphyrinate with an average value for the equatorial Fe-N bond lengths of 2.065?(3)?Å and an axial Fe-Cl distance of 2.2430?(13)?Å. The iron cation is displaced by 0.518?(1)?Å from the 24-atom mean plane of the porphyrin ring. These values are typical for high-spin iron(III) porphyrinates.

SUBMITTER: Safo MK

PROVIDER: S-EPMC3006760 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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Chlorido(2,3,7,8,12,13,17,18-octa-ethyl-porphyrinato)iron(III) dichloro-methane sesquisolvate.

Safo Martin K MK Buentello Kristin E KE Oliver Allen G AG Scheidt W Robert WR

Acta crystallographica. Section E, Structure reports online 20100605 Pt 7

The title mol-ecule, [Fe(C(36)H(44)N(4))Cl]·1.5CH(2)Cl(2), is a high-spin square-pyramidal iron(III) porphyrinate with an average value for the equatorial Fe-N bond lengths of 2.065 (3) Å and an axial Fe-Cl distance of 2.2430 (13) Å. The iron cation is displaced by 0.518 (1) Å from the 24-atom mean plane of the porphyrin ring. These values are typical for high-spin iron(III) porphyrinates. ...[more]

PMID: 21587675

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