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(Ethanolato)[2,3,7,8,12,13,17,18-octa-ethylporphyrinato(2-)]iron(III).

ABSTRACT: The title compound, [Fe(C(2)H(5)O)(C(36)H(44)N(4))], contains a five-coordinate iron-porphyrin complex with an axial eth-oxy ligand. The iron(III) atom is displaced by 0.504?(2)?Å towards the eth-oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe-N(p) distance is 2.078?(2)?Å and the Fe-O distance is 1.8232?(18)?Å. The eth-oxy C atoms are disordered in a 0.581?(12):0.419?(12) ratio. The bond angles of the Fe-O-C linkage are 128.6?(3) and 130.4?(3)°, respectively, for the major and minor occupancy C atoms.

SUBMITTER: Cheng L

PROVIDER: S-EPMC3009112 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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(Ethanolato)[2,3,7,8,12,13,17,18-octa-ethylporphyrinato(2-)]iron(III).

Cheng Lin L Xu Nan N Powell Douglas R DR Richter-Addo George B GB

Acta crystallographica. Section E, Structure reports online 20101023 Pt 11

The title compound, [Fe(C(2)H(5)O)(C(36)H(44)N(4))], contains a five-coordinate iron-porphyrin complex with an axial eth-oxy ligand. The iron(III) atom is displaced by 0.504 (2) Å towards the eth-oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe-N(p) distance is 2.078 (2) Å and the Fe-O distance is 1.8232 (18) Å. The eth-oxy C atoms are disordered in a 0.581 (12):0.419 (12) ratio. The bond angles of the Fe-O-C linkage are 128.6 (3) and 130.4 (3)°, respectively, for the majo ...[more]

PMID: 21588876

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