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2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate.

ABSTRACT: In the organic cation of the title compound, C(13)H(20)N(3) (+)·Cl(-)·H(2)O, the two pyrrolidine rings adopt twisted conformations. The pyridine ring makes dihedral angles of 14.57?(6) and 23.96?(6)° with the mean planes of the pyrrolidine rings. In the crystal structure, pairs of bifurcated inter-molecular O-H?Cl hydrogen bonds link the water mol-ecules and chloride anions into an R(4) (4)(8) ring motif. Inter-molecular N-H?Cl, C-H?Cl and C-H?O hydrogen bonds further inter-connect these rings with the organic cations into a two-dimensional network parallel to the bc plane.

SUBMITTER: Al-Dajani MT

PROVIDER: S-EPMC3007020 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate.

Al-Dajani Mohammad T M MT Abdallah Hassan H HH Mohamed Nornisah N Goh Jia Hao JH Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20100626 Pt 7

In the organic cation of the title compound, C(13)H(20)N(3) (+)·Cl(-)·H(2)O, the two pyrrolidine rings adopt twisted conformations. The pyridine ring makes dihedral angles of 14.57 (6) and 23.96 (6)° with the mean planes of the pyrrolidine rings. In the crystal structure, pairs of bifurcated inter-molecular O-H⋯Cl hydrogen bonds link the water mol-ecules and chloride anions into an R(4) (4)(8) ring motif. Inter-molecular N-H⋯Cl, C-H⋯Cl and C-H⋯O hydrogen bonds further inter-connect these rings w ...[more]

PMID: 21588023

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