Unknown

Dataset Information

0

2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate.

ABSTRACT: In the organic cation of the title compound, C(13)H(20)N(3) (+)·Cl(-)·H(2)O, the two pyrrolidine rings adopt twisted conformations. The pyridine ring makes dihedral angles of 14.57?(6) and 23.96?(6)° with the mean planes of the pyrrolidine rings. In the crystal structure, pairs of bifurcated inter-molecular O-H?Cl hydrogen bonds link the water mol-ecules and chloride anions into an R(4) (4)(8) ring motif. Inter-molecular N-H?Cl, C-H?Cl and C-H?O hydrogen bonds further inter-connect these rings with the organic cations into a two-dimensional network parallel to the bc plane.

SUBMITTER: Al-Dajani MT 

PROVIDER: S-EPMC3007020 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate.

Al-Dajani Mohammad T M MT   Abdallah Hassan H HH   Mohamed Nornisah N   Goh Jia Hao JH   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20100626 Pt 7

In the organic cation of the title compound, C(13)H(20)N(3) (+)·Cl(-)·H(2)O, the two pyrrolidine rings adopt twisted conformations. The pyridine ring makes dihedral angles of 14.57 (6) and 23.96 (6)° with the mean planes of the pyrrolidine rings. In the crystal structure, pairs of bifurcated inter-molecular O-H⋯Cl hydrogen bonds link the water mol-ecules and chloride anions into an R(4) (4)(8) ring motif. Inter-molecular N-H⋯Cl, C-H⋯Cl and C-H⋯O hydrogen bonds further inter-connect these rings w  ...[more]

Similar Datasets

Unknown 1,1'-{[1,1'-(Pyridinium-2,6-di-yl)diethyl-idyne]diimino}diguanidinium penta-chloridocadmate(II) monohydrate.
| S-EPMC2977479 | biostudies-literature
Unknown 4-tert-Butyl-pyridinium chloride-4,4'-(propane-2,2-di-yl)bis-(2,6-di-methyl-phenol)-toluene (2/2/1).
| S-EPMC3998618 | biostudies-literature
Unknown 1-(5-Amino-2,4-dinitro-phen-yl)pyridinium chloride monohydrate.
| S-EPMC3470313 | biostudies-literature
Unknown 2,6-Di-tert-butyl-4-(morpholinometh-yl)-phenol monohydrate.
| S-EPMC2960252 | biostudies-literature
Unknown 4-{[(5-Methyl-2-fur-yl)methyl-ene]hydrazinocarbon-yl}pyridinium chloride monohydrate.
| S-EPMC2977373 | biostudies-literature
Unknown 4-(5-Amino-1H-1,2,4-triazol-3-yl)pyridinium chloride monohydrate.
| S-EPMC3051743 | biostudies-literature
Unknown Crystal structure of 2,6-di-amino-pyridinium chloride.
| S-EPMC4778825 | biostudies-other
Unknown 2,6-Dimethyl-anilinium chloride monohydrate.
| S-EPMC2960140 | biostudies-literature
Unknown 1-(2,3-Di-hydroxy-prop-yl)-4-{2-[4-(di-methyl-amino)-phen-yl]vin-yl}pyridinium chloride.
| S-EPMC3914108 | biostudies-literature
Unknown 2-(1H-Pyrazol-3-yl)pyridinium chloride monohydrate.
| S-EPMC2977379 | biostudies-other