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Bis[N-(4-chloro-phen-yl)pyridine-3-carboxamide]-silver(I) nitrate.

ABSTRACT: In the title compound, [Ag(C(12)H(9)ClN(2)O)(2)]NO(3), two N atoms from two pyridine rings of two N-(4-chloro-phen-yl)pyridine-3-carboxamide ligands coordinate to the Ag(I) atom, forming a nearly linear geometry with an N-Ag-N angle of 173.41?(7)°. The crystal structure is stabilized by N-H?O, C-H?O and C-H?Cl hydrogen bonds and ?-? stacking inter-actions [centroid-centroid distance = 3.5469?(16)?Å] between the pyridyl and benzene rings. The shortest Ag?Ag distance is 3.2574?(5)?Å.

SUBMITTER: Shi CY

PROVIDER: S-EPMC3007344 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Bis[N-(4-chloro-phen-yl)pyridine-3-carboxamide]-silver(I) nitrate.

Shi Chun-Yue CY Ge Chun-Hua CH Liu Qi-Tao QT

Acta crystallographica. Section E, Structure reports online 20100703 Pt 8

In the title compound, [Ag(C(12)H(9)ClN(2)O)(2)]NO(3), two N atoms from two pyridine rings of two N-(4-chloro-phen-yl)pyridine-3-carboxamide ligands coordinate to the Ag(I) atom, forming a nearly linear geometry with an N-Ag-N angle of 173.41 (7)°. The crystal structure is stabilized by N-H⋯O, C-H⋯O and C-H⋯Cl hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.5469 (16) Å] between the pyridyl and benzene rings. The shortest Ag⋯Ag distance is 3.2574 (5) Å. ...[more]

PMID: 21588124

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