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[2,3,7,8,13,14,17,18-Octa-kis(ethyl-sulfan-yl)-5,10,15,20-porphyrazinato]zinc(II).

ABSTRACT: In the title compound, [Zn(C(32)H(40)N(8)S(8))], the Zn(II) ion is coordinated by four N atoms in a slightly distorted square-planar environment. In addition, there is a Zn?S contact involving a symmetry-related S atom which, when considered, forms a pseudo-square-pyramidal coordination with respect to the Zn(II) ion. Three of the ethyl groups are disordered over two sites with occupancy ratios of 0.841?(10):0.159?(10), 0.802?(10):0.198?(10) and 0.457?(13):0.543?(13). Weak intra-molecular C-H?N and C-H?S inter-actions contribute to the stability of the mol-ecular conformation. Inter-molecular C-H?S contacts, weak C-H?? inter-actions and ?-? stacking inter-actions [centroid-centriod distances = 3.832?(4) and 3.850?(5)?Å] contribute to the stabilization of the crystal structure.

SUBMITTER: Akkurt M

PROVIDER: S-EPMC3007436 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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[2,3,7,8,13,14,17,18-Octa-kis(ethyl-sulfan-yl)-5,10,15,20-porphyrazinato]zinc(II).

Akkurt Mehmet M Coşkun Naciye Yılmaz NY Kılıçaslan Fatma Aytan FA Yalçın Sabiha Manav SM Büyükgüngör Orhan O Gül Ahmet A

Acta crystallographica. Section E, Structure reports online 20100724 Pt 8

In the title compound, [Zn(C(32)H(40)N(8)S(8))], the Zn(II) ion is coordinated by four N atoms in a slightly distorted square-planar environment. In addition, there is a Zn⋯S contact involving a symmetry-related S atom which, when considered, forms a pseudo-square-pyramidal coordination with respect to the Zn(II) ion. Three of the ethyl groups are disordered over two sites with occupancy ratios of 0.841 (10):0.159 (10), 0.802 (10):0.198 (10) and 0.457 (13):0.543 (13). Weak intra-molecular C-H⋯N ...[more]

PMID: 21588217

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