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Cis-Bis(1,10-phenanthroline-?N,N')bis-(thio-cyanato-?N)magnesium(II).

ABSTRACT: The title compound, [Mg(NCS)(2)(C(12)H(8)N(2))(2)], has been synthesized from the hydro-thermal reaction of MgCl(2), KSCN, 1,10-phenanthroline and H(2)O. Its structure is isotypic with the Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) analogues. The Mg(II) cation has a slightly distorted octa-hedral geometry containing four N atoms from two 1,10-phenanthroline mol-ecules and two N atoms from two thio-cyanate anions. The asymmetric unit contains one-half mol-ecule, and the complete complex has 2 symmetry.

SUBMITTER: Zhao D

PROVIDER: S-EPMC3007504 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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cis-Bis(1,10-phenanthroline-κN,N')bis-(thio-cyanato-κN)magnesium(II).

Zhao Dan D Li Fei-Fei FF Sha Jiao J

Acta crystallographica. Section E, Structure reports online 20100721 Pt 8

The title compound, [Mg(NCS)(2)(C(12)H(8)N(2))(2)], has been synthesized from the hydro-thermal reaction of MgCl(2), KSCN, 1,10-phenanthroline and H(2)O. Its structure is isotypic with the Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) analogues. The Mg(II) cation has a slightly distorted octa-hedral geometry containing four N atoms from two 1,10-phenanthroline mol-ecules and two N atoms from two thio-cyanate anions. The asymmetric unit contains one-half mol-ecule, and the complete complex ha ...[more]

PMID: 21588209

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