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2-[(4-Chlorobenzyl)iminomethyl]phenol.


ABSTRACT: The title Schiff base compound, C(14)H(12)ClNO, was prepared from 4-chloro-benzyl-amine and salicyl-aldehyde. The mol-ecule is V-shaped: the dihedral angle between the aromatic rings is 67.51 (5)°. The rings are located on the opposite side of the C=N bond, giving an E configuration. An intra-molecular N-H⋯O hydrogen bond generates a S(6) ring. In the crystal structure, only weak non-classical C-H⋯O contacts are observed.

SUBMITTER: Phurat C 

PROVIDER: S-EPMC3007859 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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2-[(4-Chlorobenzyl)iminomethyl]phenol.

Phurat Chuttree C   Teerawatananond Thapong T   Muangsin Nongnuj N  

Acta crystallographica. Section E, Structure reports online 20100818 Pt 9


The title Schiff base compound, C(14)H(12)ClNO, was prepared from 4-chloro-benzyl-amine and salicyl-aldehyde. The mol-ecule is V-shaped: the dihedral angle between the aromatic rings is 67.51 (5)°. The rings are located on the opposite side of the C=N bond, giving an E configuration. An intra-molecular N-H⋯O hydrogen bond generates a S(6) ring. In the crystal structure, only weak non-classical C-H⋯O contacts are observed. ...[more]

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