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Bis[4-chloro-2-(iminomethyl)phenolato]nickel(II).

ABSTRACT: In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(7)H(5)ClNO)(2)], the Ni(II) ion, lying on an inversion center, is four-coordinated by two O and two imine N atoms from two 4-chloro-2-imino-methyl-phenolate ligands, forming a distorted square-planar geometry. In the crystal structure, mol-ecules are linked into a two-dimensional network parallel to the bc plane by C-H?O hydrogen bonds.

SUBMITTER: Hong Z

PROVIDER: S-EPMC2968681 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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Bis[4-chloro-2-(iminomethyl)phenolato]nickel(II).

Hong Zhe Z

Acta crystallographica. Section E, Structure reports online 20090213 Pt 3

In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(7)H(5)ClNO)(2)], the Ni(II) ion, lying on an inversion center, is four-coordinated by two O and two imine N atoms from two 4-chloro-2-imino-methyl-phenolate ligands, forming a distorted square-planar geometry. In the crystal structure, mol-ecules are linked into a two-dimensional network parallel to the bc plane by C-H⋯O hydrogen bonds. ...[more]

PMID: 21582061

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