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μ-Oxido-bis-({2,2'-[o-phenylenebis(nitrilo-methylidyne)]diphenolato}iron(III)) methanol monosolvate dihydrate.


ABSTRACT: The title complex, [Fe(2)(C(20)H(14)N(2)O(2))(2)O]·CH(4)O·2H(2)O, is composed of μ-oxido-bridged ferric 2,2'-[o-phenylene-bis(nitrilo-methylidyne)]diphenolate (salphen) dimers, one methanol mol-ecule and two H(2)O mol-ecules. Each iron(III) ion, surrounded by two coordinating N and O atoms from the salphen ligand and one bridging O atom, shows a five-coordinate square-pyramidal geometry. One of the two solvent water mol-ecules is disordered over three positions with occupancies of 0.44 (1), 0.37 (1) and 0.19 (1).

SUBMITTER: Yan JH 

PROVIDER: S-EPMC3007942 | biostudies-literature |

REPOSITORIES: biostudies-literature

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