Unknown

Dataset Information

0

Monoclinic modification of aquadi-n-butyl-bis-(pyrazine-2-carboxyl-ato-?N,O)tin(IV).

ABSTRACT: The asymmetric unit of the title organotin(IV) compound, [Sn(C(4)H(9))(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)], contains one-and-a-half mol-ecules. The half-mol-ecule is completed by crystallographic twofold symmetry, with its Sn and water O atoms lying on the rotation axis. Both mol-ecules feature seven-coordinate Sn atoms in trans-C(2)SnN(2)O(3) penta-gonal-bipyramidal coordination environments. The carboxyl-ate anions N,O-chelate to the Sn atom. In the crystal, the carboxyl-ate O atoms not involved in coordination serve as acceptors for O-H?O hydrogen bonds from adjacent water mol-ecules, generating a three-dimensional network.

SUBMITTER: Ng SW 

PROVIDER: S-EPMC3008135 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Monoclinic modification of aquadi-n-butyl-bis-(pyrazine-2-carboxyl-ato-κN,O)tin(IV).

Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20100821 Pt 9

The asymmetric unit of the title organotin(IV) compound, [Sn(C(4)H(9))(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)], contains one-and-a-half mol-ecules. The half-mol-ecule is completed by crystallographic twofold symmetry, with its Sn and water O atoms lying on the rotation axis. Both mol-ecules feature seven-coordinate Sn atoms in trans-C(2)SnN(2)O(3) penta-gonal-bipyramidal coordination environments. The carboxyl-ate anions N,O-chelate to the Sn atom. In the crystal, the carboxyl-ate O atoms not involved i  ...[more]

Similar Datasets

Unknown Aquadi-n-but-yl(5-methyl-pyrazine-2-carboxyl-ato)tin(IV) methanol solvate.
| S-EPMC2961732 | biostudies-literature
Unknown Bis(5-methyl-pyrazine-2-carboxyl-ato)-diphenyl-tin(IV).
| S-EPMC2961826 | biostudies-literature
Unknown Dimethyl-bis-(pyrazine-2-carboxyl-ato-κ(2)N(1),O)tin(IV).
| S-EPMC3515132 | biostudies-literature
Unknown Monoclinic modification of di-n-butyl-dichlorido(1,10-phenanthroline-?N,N')tin(IV).
| S-EPMC3011636 | biostudies-literature
Unknown Di-tert-butyl-chlorido(pyrrolidine-1-dithio-carboxyl-ato-κS,S')tin(IV).
| S-EPMC2914963 | biostudies-literature
Unknown (Ferrocene-carboxyl-ato-κO)triphenyl-tin(IV).
| S-EPMC3006984 | biostudies-literature
Unknown 2-(Ethoxy-carbon-yl)quinolinium butyl-trichlorido(quinoline-2-carboxyl-ato-κN,O)stannate(IV).
| S-EPMC2960164 | biostudies-literature
Unknown 3-Meth-oxy-carbonyl-1-methyl-pyrazinium tetra-chlorido(pyrazine-2-carboxyl-ato-κN,O)stannate(IV).
| S-EPMC3051442 | biostudies-literature
Unknown Diaqua-(5-methyl-pyrazine-2-carboxyl-ato-κN,O)iron(II).
| S-EPMC2968011 | biostudies-literature
Unknown Diaqua-bis(pyrazine-2-carboxyl-ato-κN,O)manganese(II) dihydrate.
| S-EPMC2961000 | biostudies-literature