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(Ferrocene-carboxyl-ato-κO)triphenyl-tin(IV).

ABSTRACT: In the title compound, [FeSn(C(5)H(5))(C(6)H(5))(3)(C(6)H(4)O(2))], the Sn(IV) atom displays a distorted tetra-hedral coordination geometry, provided by one O atom of the monodentate ferrocene-carboxyl-ate ligand [Sn-O = 2.079 (2) Å] and by three C atoms of the three phenyl groups [average Sn-C = 2.130 (4) Å]. No classic hydrogen bonds or inter-molecular inter-actions are observed in the crystal.

SUBMITTER: Yu Y

PROVIDER: S-EPMC3006984 | biostudies-literature |

REPOSITORIES: biostudies-literature

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(Ethanol-κO)[2-(4-hydroxy-phen-yl)quinoline-4-carboxyl-ato-κO]triphenyl-tin(IV).

Project description:The Sn atom in the title mol-ecule, [Sn(C(6)H(5))(3)(C(16)H(10)NO(3))(C(2)H(6)O)], shows a trans-C(3)SnO(2) trigonal bipyramidal coord-in-ation. Adjacent mol-ecules are linked by O-H⋯O and O-H⋯N hydrogen bonds into a two-dimensional array parallel to (100). The ethanol ligand is disordered, with two sites of equal occupancy being resolved for the ethyl group.

| S-EPMC2977554 | biostudies-literature

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Project description:In the title compound, [Sn(C(6)H(5))(3)Cl(C(2)H(6)OS)], the Sn(IV) atom is coordinated by three phenyl groups, a chloride ion and a dimethyl sulfoxide mol-ecule in a distorted trigonal-bipyramidal geometry. In the crystal, adjacent mol-ecules are linked through inter-molecular C-H⋯Cl hydrogen bonds, weak C-H⋯π inter-actions and π-π inter-actions [centroid-centroid distance = 3.934 (3) Å. An intra-molecular C-H⋯π inter-action is also observed.

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(Methanol-κO)(2-methyl-3-nitro-benzoato-κO)triphenyl-tin(IV).

Project description:The five-coordinate Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(6)NO(4))(CH(3)OH)], exists in a trans-C(3)SnO(2) trigonal-bipyramidal coordination polyhedron of which the O atoms of the methanol mol-ecule and carboxyl-ate group occupy the apical sites. In the crystal, adjacent mol-ecules are linked by inter-molecular O-H⋯O inter-actions, generating a helical hydrogen-bonded chain running along the b axis.

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Project description:The Sn(IV) atom in the monomeric title compound, [Sn(C(6)H(5))(3)(C(9)H(9)O(3))] exists in a distorted SnC(3)O tetra-hedral geometry. In the crystal structure, inversion dimers arise from pairs of O-H⋯O hydrogen bonds.

| S-EPMC2959787 | biostudies-literature

(μ-2,3-Dihydroxy-butane-1,4-dithiol-ato)bis-[triphenyl-tin(IV)].

Project description:In the title compound, [Sn(2)(C(6)H(5))(6)(C(4)H(8)O(2)S(2))], the geometry around the Sn atoms is distorted tetra-hedral. The hydr-oxy groups are involved in O-H⋯O hydrogen bonding, which connects mol-ecules into centrosymmetric dimers.

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Bis(5-bromo-pyridine-2-carboxyl-ato-κO)triphenyl-anti-mony(V).

Project description:In the title compound, [Sb(C(6)H(5))(3)(C(6)H(3)BrNO(2))(2)], the Sb center has a distorted trigonal-bipyramidal geometry, with two carboxyl-ate O atoms of two 5-bromo-pyridine-2-carboxyl-ate ligands in equatorial positions and three phenyl ligands in axial positions. The crystal structure is stabilized by C-H⋯Br hydrogen bonds and inter-molecular C-Br⋯π inter-actions [C⋯π = 3.57 (1) Å].

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Bis(ferrocene-carboxyl-ato-κO)bis-(2-pyridyl-methanol-κN,O)cobalt(II).

Project description:The title complex mol-ecule, [Fe(2)Co(C(5)H(5))(2)(C(6)H(4)O(2))(2)(C(6)H(7)NO)(2)], has a crystallographic imposed centre of symmetry. The Co(II) atom displays a distorted octa-hedral coordination geometry, provided by the O atoms of two monodentate ferrocene-carboxyl-ate anions and by the N and O atoms of two 2-pyridyl-methanol mol-ecule. The mol-ecular conformation is stabilized by intra-molecular C-H⋯O hydrogen bonds.

| S-EPMC3007041 | biostudies-literature

Bis(5-methyl-pyrazine-2-carboxyl-ato)-diphenyl-tin(IV).

Project description:In the mol-ecule of the title compound, [Sn(C(6)H(5))(2)(C(6)H(5)N(2)O(2))(2)], two O and one N atoms from the two 5-methyl-pyrazine-2-carboxyl-ate ligands and one C atom of a phenyl group form a distorted square-planar arrangement in the equatorial plane around the Sn atom, while the distorted octa-hedral coordination is completed by an N atom of one of the 5-methyl-pyrazine-2-carboxyl-ate ligands and a C atom of the other phenyl group in the axial positions. In the crystal structure, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers.

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Tricyclo-hexyl(piperidine-1-dithio-carboxyl-ato-κS)tin(IV).

Project description:In the title compound, [Sn(C(6)H(11))(3)(C(6)H(10)NS(2))], the Sn(IV) atom is tetra-coordinated by three C atoms from cyclo-hexyl groups and one S atom from a piperidine-dithio-carboxyl-ate anion. The coordination geometry is distorted tetra-hedral, with Sn-C bond lengths in the range 2.133 (6)-2.188 (6) Å and with an Sn-S bond length of 2.4516 (19) Å. The nonbonded S atom of the piperidine-dithio-carboxyl-ate anion makes an Sn⋯S contact of 3.174 (3) Å.

| S-EPMC2961956 | biostudies-literature

Chloridomethyl-phen-yl(quinoline-2-carboxyl-ato-?N,O)tin(IV).

Project description:The Sn atom in the title compound, [Sn(CH(3))(C(6)H(5))(C(10)H(6)NO(2))Cl], shows a distorted C(2)SnNOCl trigonal-bipyramidal coordination; the apical sites are occupied by the N and Cl atoms.

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