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(Ferrocene-carboxyl-ato-κO)triphenyl-tin(IV).

ABSTRACT: In the title compound, [FeSn(C(5)H(5))(C(6)H(5))(3)(C(6)H(4)O(2))], the Sn(IV) atom displays a distorted tetra-hedral coordination geometry, provided by one O atom of the monodentate ferrocene-carboxyl-ate ligand [Sn-O = 2.079 (2) Å] and by three C atoms of the three phenyl groups [average Sn-C = 2.130 (4) Å]. No classic hydrogen bonds or inter-molecular inter-actions are observed in the crystal.

SUBMITTER: Yu Y

PROVIDER: S-EPMC3006984 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Chlorido(dimethyl sulfoxide-κO)triphenyl-tin(IV).

Project description:In the title compound, [Sn(C(6)H(5))(3)Cl(C(2)H(6)OS)], the Sn(IV) atom is coordinated by three phenyl groups, a chloride ion and a dimethyl sulfoxide mol-ecule in a distorted trigonal-bipyramidal geometry. In the crystal, adjacent mol-ecules are linked through inter-molecular C-H⋯Cl hydrogen bonds, weak C-H⋯π inter-actions and π-π inter-actions [centroid-centroid distance = 3.934 (3) Å. An intra-molecular C-H⋯π inter-action is also observed.

| S-EPMC2971969 | biostudies-literature

(Methanol-κO)(2-methyl-3-nitro-benzoato-κO)triphenyl-tin(IV).

Project description:The five-coordinate Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(6)NO(4))(CH(3)OH)], exists in a trans-C(3)SnO(2) trigonal-bipyramidal coordination polyhedron of which the O atoms of the methanol mol-ecule and carboxyl-ate group occupy the apical sites. In the crystal, adjacent mol-ecules are linked by inter-molecular O-H⋯O inter-actions, generating a helical hydrogen-bonded chain running along the b axis.

| S-EPMC3007999 | biostudies-literature

(Ethanol-?O)[2-(4-hydroxy-phen-yl)quinoline-4-carboxyl-ato-?O]triphenyl-tin(IV).

Project description:The Sn atom in the title mol-ecule, [Sn(C(6)H(5))(3)(C(16)H(10)NO(3))(C(2)H(6)O)], shows a trans-C(3)SnO(2) trigonal bipyramidal coord-in-ation. Adjacent mol-ecules are linked by O-H?O and O-H?N hydrogen bonds into a two-dimensional array parallel to (100). The ethanol ligand is disordered, with two sites of equal occupancy being resolved for the ethyl group.

| S-EPMC2977554 | biostudies-literature

(μ-2,3-Dihydroxy-butane-1,4-dithiol-ato)bis-[triphenyl-tin(IV)].

Project description:In the title compound, [Sn(2)(C(6)H(5))(6)(C(4)H(8)O(2)S(2))], the geometry around the Sn atoms is distorted tetra-hedral. The hydr-oxy groups are involved in O-H⋯O hydrogen bonding, which connects mol-ecules into centrosymmetric dimers.

| S-EPMC2979966 | biostudies-literature

Tricyclo-hexyl(piperidine-1-dithio-carboxyl-ato-κS)tin(IV).

Project description:In the title compound, [Sn(C(6)H(11))(3)(C(6)H(10)NS(2))], the Sn(IV) atom is tetra-coordinated by three C atoms from cyclo-hexyl groups and one S atom from a piperidine-dithio-carboxyl-ate anion. The coordination geometry is distorted tetra-hedral, with Sn-C bond lengths in the range 2.133 (6)-2.188 (6) Å and with an Sn-S bond length of 2.4516 (19) Å. The nonbonded S atom of the piperidine-dithio-carboxyl-ate anion makes an Sn⋯S contact of 3.174 (3) Å.

| S-EPMC2961956 | biostudies-literature

Chloridomethyl-phen-yl(quinoline-2-carboxyl-ato-?N,O)tin(IV).

Project description:The Sn atom in the title compound, [Sn(CH(3))(C(6)H(5))(C(10)H(6)NO(2))Cl], shows a distorted C(2)SnNOCl trigonal-bipyramidal coordination; the apical sites are occupied by the N and Cl atoms.

| S-EPMC3007314 | biostudies-literature

Dimethyl-bis-(pyrazine-2-carboxyl-ato-?(2)N(1),O)tin(IV).

Project description:In the title compound, [Sn(CH(3))(2)(C(5)H(3)N(2)O(2))(2)], the Sn(IV) atom is twice N,O-chelated by two pyrazine-2-carboxyl-ate ligands. The distorted six-coordination is completed by two tin-bound methyl C atoms. The C(2)N(2)O(2) donor set defines a skewed trapezoidal-bipyramidal geometry. Inter-molecular ?-? inter-actions between the pyrazine rings [centroid-centroid distance = 3.8112?(13)?Å] are observed.

| S-EPMC3515132 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-cyclo-hex-3-ene-1-carboxyl-ato].

Project description:The title compound, [Sn(CH(3))(3)(C(7)H(9)O(2))](n), forms an extended zigzag chain structure propagating parallel to [010]. The Sn atom is in a slightly distorted trigonal-bipyramidal coordination environment with two carboxyl-ate O atoms in the axial and the three methyl groups in equatorial sites. The cyclo-hexene ring has a distorted half-boat conformation. There is an intra-molecular C-H?O hydrogen bond.

| S-EPMC2980015 | biostudies-literature

[5-(4-Bromo-phenoxy-meth-yl)-1,3,4-thia-diazole-2-thiol-ato]triphenyl-tin(IV).

Project description:In title compound, [Sn(C(6)H(5))(3)(C(9)H(6)BrN(2)OS(2))], the Sn atom is five-coordinated and the 1,3,4-thia-diazole-2-thiol ligand acts as an S,N-bidentate chelating ligand. The five-coordinate Sn(IV) atom forms four primary bonds, three to the phenyl groups and one to the S atom. Thus, the title complex has a distorted cis-trigonal bipyramidal geometry with the S atom and two C atoms occupying the equatorial plane, whereas the N atom and another C atom are in axial positions. In addition, there is a weak intramolecular Sn?N interaction. The crystal structure involves weak intra-molecular C-H?N and inter-molecular C-H?Br hydrogen bonding.

| S-EPMC2977584 | biostudies-literature

Di-tert-butyl-chlorido(pyrrolidine-1-dithio-carboxyl-ato-κS,S')tin(IV).

Project description:The title compound, [Sn(C(4)H(9))(2)(C(5)H(8)NS(2))Cl], contains two mol-ecules in the asymmetric unit, with similar conformations. In both mol-ecules, the Sn atom adopts a distorted trigonal-bipyramidal geometry arising from two C atoms, one Cl atom and two S atoms from the bidentate dithio-carbamate ligand, with one Sn-S bond much longer than the other. One C atom of the pyrrolidine ring is disordered equally over two sites.

| S-EPMC2914963 | biostudies-literature

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