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(Heptanedioato-?O,O')bis-(1,10-phenanthroline-?N,N')zinc(II) hexa-hydrate.

ABSTRACT: In the crystal structure of the title compound, [Zn(C(7)H(10)O(4))(C(12)H(8)N(2))(2)]·6H(2)O, the Zn(II) atom is coordinated by two carboxyl-ate O atoms of a mono-bidentate chelating pimelate anion (pimelic acid is hepta-nedioic acid) and four N atoms of two phenanthroline ligands, forming a considerably distorted octa-hedral ZnN(4)O(2) coordination geometry. The complexes are assembled into a three-dimensional network via C-H?O, C-H?? and ?-? inter-actions. The mean inter-planar distance between adjacent phenanthroline ligands is 3.399?(2)?Å.

SUBMITTER: Lin JL

PROVIDER: S-EPMC2961045 | biostudies-literature | 2008 Mar

REPOSITORIES: biostudies-literature

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(Heptanedioato-κO,O')bis-(1,10-phenanthroline-κN,N')zinc(II) hexa-hydrate.

Lin Jian-Li JL Wang Yuan-Yuan YY

Acta crystallographica. Section E, Structure reports online 20080307 Pt 4

In the crystal structure of the title compound, [Zn(C(7)H(10)O(4))(C(12)H(8)N(2))(2)]·6H(2)O, the Zn(II) atom is coordinated by two carboxyl-ate O atoms of a mono-bidentate chelating pimelate anion (pimelic acid is hepta-nedioic acid) and four N atoms of two phenanthroline ligands, forming a considerably distorted octa-hedral ZnN(4)O(2) coordination geometry. The complexes are assembled into a three-dimensional network via C-H⋯O, C-H⋯π and π-π inter-actions. The mean inter-planar distance betwee ...[more]

PMID: 21201992

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