Unknown

Dataset Information

0

(Heptanedioato-?O,O')bis-(1,10-phenanthroline-?N,N')zinc(II) hexa-hydrate.

ABSTRACT: In the crystal structure of the title compound, [Zn(C(7)H(10)O(4))(C(12)H(8)N(2))(2)]·6H(2)O, the Zn(II) atom is coordinated by two carboxyl-ate O atoms of a mono-bidentate chelating pimelate anion (pimelic acid is hepta-nedioic acid) and four N atoms of two phenanthroline ligands, forming a considerably distorted octa-hedral ZnN(4)O(2) coordination geometry. The complexes are assembled into a three-dimensional network via C-H?O, C-H?? and ?-? inter-actions. The mean inter-planar distance between adjacent phenanthroline ligands is 3.399?(2)?Å.

SUBMITTER: Lin JL 

PROVIDER: S-EPMC2961045 | biostudies-literature | 2008 Mar

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(Heptanedioato-κO,O')bis-(1,10-phenanthroline-κN,N')zinc(II) hexa-hydrate.

Lin Jian-Li JL   Wang Yuan-Yuan YY  

Acta crystallographica. Section E, Structure reports online 20080307 Pt 4

In the crystal structure of the title compound, [Zn(C(7)H(10)O(4))(C(12)H(8)N(2))(2)]·6H(2)O, the Zn(II) atom is coordinated by two carboxyl-ate O atoms of a mono-bidentate chelating pimelate anion (pimelic acid is hepta-nedioic acid) and four N atoms of two phenanthroline ligands, forming a considerably distorted octa-hedral ZnN(4)O(2) coordination geometry. The complexes are assembled into a three-dimensional network via C-H⋯O, C-H⋯π and π-π inter-actions. The mean inter-planar distance betwee  ...[more]

Similar Datasets

Unknown Diaqua-bis-(1,10-phenanthroline-?N,N')manganese(II) sulfate hexa-hydrate.
| S-EPMC3009039 | biostudies-literature
Unknown Poly[[(1,10-phenanthroline)(?-l-tartrato)zinc] hexa-hydrate].
| S-EPMC3152042 | biostudies-literature
Unknown (Formato-?O)bis-(1,10-phenanthroline-?N,N')copper(II) formate hexa-hydrate.
| S-EPMC2960151 | biostudies-literature
Unknown (?-Butane-1,2,3,4-tetra-carboxyl-ato)bis-[triaqua-(1,10-phenanthroline)nickel(II)] hexa-hydrate.
| S-EPMC3011463 | biostudies-literature
Unknown Diaqua-bis-(1,10-phenanthroline-?N,N')cadmium sulfate hexa-hydrate.
| S-EPMC3247531 | biostudies-literature
Unknown Bis(1,10-phenanthroline-?N,N')(phenyl-acetato-?O)copper(II) phenyl-acetate hexa-hydrate.
| S-EPMC2959544 | biostudies-literature
Unknown [Malonato(2-)-?O,O']bis-(1,10-phenanthroline-?N,N')zinc(II) penta-hydrate.
| S-EPMC3050196 | biostudies-literature
Unknown Tris(1,10-phenanthroline-κN,N')zinc(II) bis-(4-bromo-benzoate) 6.5-hydrate.
| S-EPMC2983930 | biostudies-literature
Unknown Bis[tetra-aqua-(1,10-phenanthroline-?N,N')cobalt(II)] hexa-aqua-cobalt(II) bis-[3,5-bis-(carboxyl-atometh-oxy)benzoate] tetra-hydrate.
| S-EPMC3011475 | biostudies-literature
Unknown Aqua-(4-bromo-benzoato-κO)bis-(1,10-phenanthroline-κN,N')zinc(II) 4-bromo-benzoate 1.5-hydrate.
| S-EPMC3009099 | biostudies-literature