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(Formato-?O)bis-(1,10-phenanthroline-?N,N')copper(II) formate hexa-hydrate.

ABSTRACT: In the title compound, [Cu(CHO(2))(C(12)H(8)N(2))(2)]CHO(2)·6H(2)O, the Cu atom is coordinated in a distorted trigonal-bipyramidal fashion by an O atom of the formate ligand and four N atoms of two phenanthroline ligands with Cu-O and Cu-N distances of 2.020?(3) and 1.978?(3)-2.177?(3)?Å, respectively. Hydrogen bonding O-H?O between water molecules and between water anions as well as ?-? inter-actions [centroid-centroid distances between phen rings = 3.38?(7) and 3.40?(5)?Å] are responsible for the supra-molecular assembly.

SUBMITTER: Xu W

PROVIDER: S-EPMC2960151 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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(Formato-κO)bis-(1,10-phenanthroline-κN,N')copper(II) formate hexa-hydrate.

Xu Wei W Lin Jian-Li JL Xie Hong-Zhen HZ Zhang Ming M

Acta crystallographica. Section E, Structure reports online 20081108 Pt 12

In the title compound, [Cu(CHO(2))(C(12)H(8)N(2))(2)]CHO(2)·6H(2)O, the Cu atom is coordinated in a distorted trigonal-bipyramidal fashion by an O atom of the formate ligand and four N atoms of two phenanthroline ligands with Cu-O and Cu-N distances of 2.020 (3) and 1.978 (3)-2.177 (3) Å, respectively. Hydrogen bonding O-H⋯O between water molecules and between water anions as well as π-π inter-actions [centroid-centroid distances between phen rings = 3.38 (7) and 3.40 (5) Å] are responsible for ...[more]

PMID: 21581117

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