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Trans-Carbonyl-chloridobis[tris(naph-thalen-1-yl)-phosphane-?P]rhodium(I) acetone trisolvate.

ABSTRACT: In the title compound, trans-[RhCl{P(C(10)H(7))(3)}(2)(CO)]·3C(3)H(6)O, where P(C(10)H(7))(3) is trinaphthyl-phosphine, the Rh-P bond lengths are 2.3360?(10) and 2.3258?(10)?Å, while the Rh-Cl bond length is 2.3525?(11)?Å. The coordination around the Rh atom shows a slightly distorted square-planar arrangement.

SUBMITTER: Meijboom R

PROVIDER: S-EPMC3201328 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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trans-Carbonyl-chloridobis[tris(naph-thalen-1-yl)-phosphane-κP]rhodium(I) acetone trisolvate.

Meijboom Reinout R

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

In the title compound, trans-[RhCl{P(C(10)H(7))(3)}(2)(CO)]·3C(3)H(6)O, where P(C(10)H(7))(3) is trinaphthyl-phosphine, the Rh-P bond lengths are 2.3360 (10) and 2.3258 (10) Å, while the Rh-Cl bond length is 2.3525 (11) Å. The coordination around the Rh atom shows a slightly distorted square-planar arrangement. ...[more]

PMID: 22065702

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