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4-Bromo-anilinium perchlorate 18-crown-6 clathrate.


ABSTRACT: The reaction of 4-bromo-aniline, 18-crown-6, and perchloric acid in methanol yields the title compound, C(6)H(7)BrN(+)·ClO(4) (-)·C(12)H(24)O(6), in which the protonated -NH(3) (+) group forms three bifurcated N-H?O hydrogen bonds to the O atoms of the crown ether.

SUBMITTER: Guo M 

PROVIDER: S-EPMC3009328 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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4-Bromo-anilinium perchlorate 18-crown-6 clathrate.

Guo Min M   Zhao Min Min MM  

Acta crystallographica. Section E, Structure reports online 20101020 Pt 11


The reaction of 4-bromo-aniline, 18-crown-6, and perchloric acid in methanol yields the title compound, C(6)H(7)BrN(+)·ClO(4) (-)·C(12)H(24)O(6), in which the protonated -NH(3) (+) group forms three bifurcated N-H⋯O hydrogen bonds to the O atoms of the crown ether. ...[more]

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