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4-Methyl-anilinium perchlorate 18-crown-6 clathrate.

ABSTRACT: In the title compound, C(7)H(10)N(+)·ClO(4) (-)·C(12)H(24)O(6), the 4-methyl-anilinium cation inter-acts with an 18-crown-6 mol-ecule forming a rotator-stator-like structure through bifurcated N-H?(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether mol-ecule. All three components of the structure possess mirror symmetry. The benzene ring is inclined to the mean plane of the crown ether molecule by 86.84?(8)°.

SUBMITTER: Wang YF

PROVIDER: S-EPMC3254523 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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4-Methyl-anilinium perchlorate 18-crown-6 clathrate.

Wang Yu-Feng YF

Acta crystallographica. Section E, Structure reports online 20111221 Pt 1

In the title compound, C(7)H(10)N(+)·ClO(4) (-)·C(12)H(24)O(6), the 4-methyl-anilinium cation inter-acts with an 18-crown-6 mol-ecule forming a rotator-stator-like structure through bifurcated N-H⋯(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether mol-ecule. All three components of the structure possess mirror symmetry. The benzene ring is inclined to the mean plane of the crown ether molecule by 86.84 (8)°. ...[more]

PMID: 22259469

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