2,4,5-Trichloro-anilinium perchlorate 18-crown-6 clathrate.

ABSTRACT: In the title compound, C(6)H(5)Cl(3)N(+)·ClO(4) (-)·C(12)H(24)O(6), the perchlorate anion is disordered over two orientations in a 0.666?(17):0.334?(17) ratio. The ammonium group of the organic cation inserts into the crown ether ring and forms three bifurcated N-H?(O,O) hydrogen bonds to generate a supra-molecular complex. The macrocycle has approximate D(3d) local symmetry.

SUBMITTER: Xu J 

PROVIDER: S-EPMC3295508 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature