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Bis[4-chloro-N'-(2-pyridyl-methyl-idene)benzohydrazidato]cobalt(III) nitrate sesquihydrate.

ABSTRACT: In the title compound, [Co(C(13)H(9)ClN(3)O)(2)]NO(3)·1.5H(2)O, the central Co(3+) atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octa-hedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully occupied water mol-ecules, and the nitrate anion via classical inter-molecular O-H?O and O-H?N hydrogen bonds and weak C-H?O contacts.

SUBMITTER: Wu D

PROVIDER: S-EPMC3011380 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Bis[4-chloro-N'-(2-pyridyl-methyl-idene)benzohydrazidato]cobalt(III) nitrate sesquihydrate.

Wu Dayu D Zhao Yan Y Ye Hui H Wu Genhua G

Acta crystallographica. Section E, Structure reports online 20101113 Pt 12

In the title compound, [Co(C(13)H(9)ClN(3)O)(2)]NO(3)·1.5H(2)O, the central Co(3+) atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octa-hedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully occupied water mol-ecules, and the nitrate anion via classical inter-molecular O-H⋯O and O-H⋯N hydrogen bonds and weak C-H⋯O contacts. ...[more]

PMID: 21589256

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