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{4-Chloro-N'-[(2-oxidonaphthalen-1-yl-?O)methyl-idene]benzohydrazidato-?(2) N',O}di-methyl-tin(IV).

ABSTRACT: In the title complex, [Sn(CH3)2(C18H11ClN2O2)], the Sn(IV) ion is coordinated by two O atoms and an N atom from a 4-chloro-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal-bipyramidal geometry [Sn-O = 2.092?(3) and 2.144?(3)?Å; Sn-N = 2.160?(4)?Å]. The dihedral angle between the naphthalene ring system and the benzene ring is 8.6?(2)°. In the crystal, adjacent mol-ecules are linked by weak C-H?O hydrogen bonds, forming a chain along the b-axis direction.

SUBMITTER: Cui J

PROVIDER: S-EPMC3885012 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature

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{4-Chloro-N'-[(2-oxidonaphthalen-1-yl-κO)methyl-idene]benzohydrazidato-κ(2) N',O}di-methyl-tin(IV).

Cui Jichun J Qiao Yanling Y Wang Fei F

Acta crystallographica. Section E, Structure reports online 20131130 Pt 12

In the title complex, [Sn(CH3)2(C18H11ClN2O2)], the Sn(IV) ion is coordinated by two O atoms and an N atom from a 4-chloro-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal-bipyramidal geometry [Sn-O = 2.092 (3) and 2.144 (3) Å; Sn-N = 2.160 (4) Å]. The dihedral angle between the naphthalene ring system and the benzene ring is 8.6 (2)°. In the crystal, adjacent mol-ecules are linked by weak C-H⋯O hydrogen bonds, formi ...[more]

PMID: 24454187

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