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Bromidotricarbon-yl[4-chloro-N-(2-pyridyl-methyl-idene)aniline-?N,N']rhenium(I).

ABSTRACT: In the title compound, [ReBr(C(12)H(9)ClN(2))(CO)(3)], the Re(I) atom has a distorted octa-hedral configuration with the three carbonyl ligands showing a facial arrangement. The main distortion of the octa-hedron is due to a small bite angle of the chelating bidentate diimine ligand [N-Re-N = 75.3?(3)°].

SUBMITTER: Khalaj M

PROVIDER: S-EPMC3011448 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Bromidotricarbon-yl[4-chloro-N-(2-pyridyl-methyl-idene)aniline-κN,N']rhenium(I).

Khalaj Mehdi M Dehghanpour Saeed S Aleeshah Roghaieh R Mahmoudi Ali A

Acta crystallographica. Section E, Structure reports online 20101124 Pt 12

In the title compound, [ReBr(C(12)H(9)ClN(2))(CO)(3)], the Re(I) atom has a distorted octa-hedral configuration with the three carbonyl ligands showing a facial arrangement. The main distortion of the octa-hedron is due to a small bite angle of the chelating bidentate diimine ligand [N-Re-N = 75.3 (3)°]. ...[more]

PMID: 21589315

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