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Poly[di-?(2)-chlorido-?(2)-(1,4-dioxane-?O:O')-cadmium(II)].

ABSTRACT: In the title complex, [CdCl(2)(C(4)H(8)O(2))](n), two different Cd(II) ions are present, one in a general position and one with site symmetry 2. The Cd(II) ions are coordinated by two O atoms from two 1,4-dioxane ligands and four chloride anions in a slightly distorted octa-hedral geometry and is connected to neighboring Cd(II) ions by two bridging chloride anions, generating infinite linear chains along the a axis. These chains are further inter-connected by bridging 1,4-dioxane ligands, affording a three-dimensional network.

SUBMITTER: Wang JQ

PROVIDER: S-EPMC3011614 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Poly[di-μ(2)-chlorido-μ(2)-(1,4-dioxane-κO:O')-cadmium(II)].

Wang Jian-Qiang JQ Du Ren-Jun RJ Wang Wei W Luan Chang-Jun CJ Guo Cheng C

Acta crystallographica. Section E, Structure reports online 20101127 Pt 12

In the title complex, [CdCl(2)(C(4)H(8)O(2))](n), two different Cd(II) ions are present, one in a general position and one with site symmetry 2. The Cd(II) ions are coordinated by two O atoms from two 1,4-dioxane ligands and four chloride anions in a slightly distorted octa-hedral geometry and is connected to neighboring Cd(II) ions by two bridging chloride anions, generating infinite linear chains along the a axis. These chains are further inter-connected by bridging 1,4-dioxane ligands, afford ...[more]

PMID: 21589339

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