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(S)-3-Bromo-4-diallyl-amino-5-[(1R,2S,5R)-2-isopropyl-5-methyl-cyclo-hex-yloxy]furan-2(5H)-one.


ABSTRACT: The title compound, C(20)H(30)BrNO(3), was obtained via a tandem asymmetric Michael addition-elimination reaction of 3,4-dibromo-5-(S)-(l-menth-yloxy)-2(5H)-furan-one and diallyl-amine in the presence of potassium fluoride. In the mol-ecule, the five-membered furan-one ring is approximately planar [maximum atomic deviation = 0.030?(3)?Å], and the six-membered cyclo-hexane ring adopts a chair conformation.

SUBMITTER: Fu JH 

PROVIDER: S-EPMC3011618 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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(S)-3-Bromo-4-diallyl-amino-5-[(1R,2S,5R)-2-isopropyl-5-methyl-cyclo-hex-yloxy]furan-2(5H)-one.

Fu Jian-Hua JH   Wang Zhao-Yang ZY   Li Jian-Xiao JX   Tan Yue-He YH  

Acta crystallographica. Section E, Structure reports online 20101124 Pt 12


The title compound, C(20)H(30)BrNO(3), was obtained via a tandem asymmetric Michael addition-elimination reaction of 3,4-dibromo-5-(S)-(l-menth-yloxy)-2(5H)-furan-one and diallyl-amine in the presence of potassium fluoride. In the mol-ecule, the five-membered furan-one ring is approximately planar [maximum atomic deviation = 0.030 (3) Å], and the six-membered cyclo-hexane ring adopts a chair conformation. ...[more]

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