Unknown

Dataset Information

0

(5S)-3-Chloro-4-diallyl-amino-5-[(1R,2S,5R)-2-isopropyl-5-methyl-cyclo-hex-yloxy]furan-2(5H)-one.


ABSTRACT: The title compound, C(20)H(30)ClNO(3), was obtained via a tandem asymmetric Michael addition-elimination reaction of (5S)-3,4-dichloro-5-(l-menth-yloxy)-2(5H)-furan-one and diallyl-amine in the presence of potassium fluoride. The mol-ecular structure contains an approximately planar five-membered furan-one ring [maximum atomic deviation = 0.0221?(3)?Å] and a six-membered ring adopting a chair conformation.

SUBMITTER: Huang DN 

PROVIDER: S-EPMC3213497 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

altmetric image

Publications

(5S)-3-Chloro-4-diallyl-amino-5-[(1R,2S,5R)-2-isopropyl-5-methyl-cyclo-hex-yloxy]furan-2(5H)-one.

Huang Dong-Na DN   Tan Yue-He YH   Fu Jian-Hua JH   Wang Zhao-Yang ZY  

Acta crystallographica. Section E, Structure reports online 20110716 Pt 8


The title compound, C(20)H(30)ClNO(3), was obtained via a tandem asymmetric Michael addition-elimination reaction of (5S)-3,4-dichloro-5-(l-menth-yloxy)-2(5H)-furan-one and diallyl-amine in the presence of potassium fluoride. The mol-ecular structure contains an approximately planar five-membered furan-one ring [maximum atomic deviation = 0.0221 (3) Å] and a six-membered ring adopting a chair conformation. ...[more]

Similar Datasets

| S-EPMC3011618 | biostudies-literature
| S-EPMC3051989 | biostudies-literature
| S-EPMC3050327 | biostudies-literature
| S-EPMC3120571 | biostudies-literature
| S-EPMC3007345 | biostudies-literature
| S-EPMC4158531 | biostudies-literature
| S-EPMC6505609 | biostudies-literature
| S-EPMC3275078 | biostudies-literature
| S-EPMC3588340 | biostudies-literature
| S-EPMC3648263 | biostudies-literature