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(R)-[1-(2-Chloro-phen-yl)-2-meth-oxy-2-oxoeth-yl][2-(thio-phen-2-yl)eth-yl]ammonium (+)-camphor-10-sulfonate acetone monosolvate.

ABSTRACT: The title compound, C(15)H(17)ClNO(2)S(+)·C(10)H(15)O(4)S(-)·C(3)H(6)O, was synthesized by N-alkyl-ation of ?-amino-(2-chloro-phen-yl)acetate with 2-thienylethyl p-toluene-sulfonate, followed by reaction with (+)-camphor-10-sulfonic acid. In the crystal, the cations and anions are linked through N-H?O hydrogen bonds. The thio-phene ring of the cation was found to be disordered over two sites, with refined occupancies of 0.798?(4) and 0.202?(4).

SUBMITTER: Liang YS

PROVIDER: S-EPMC3011721 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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(R)-[1-(2-Chloro-phen-yl)-2-meth-oxy-2-oxoeth-yl][2-(thio-phen-2-yl)eth-yl]ammonium (+)-camphor-10-sulfonate acetone monosolvate.

Liang Yan-Shu YS Mu Shuai S Liu Ying Y Liu Deng-Ke DK

Acta crystallographica. Section E, Structure reports online 20101110 Pt 12

The title compound, C(15)H(17)ClNO(2)S(+)·C(10)H(15)O(4)S(-)·C(3)H(6)O, was synthesized by N-alkyl-ation of α-amino-(2-chloro-phen-yl)acetate with 2-thienylethyl p-toluene-sulfonate, followed by reaction with (+)-camphor-10-sulfonic acid. In the crystal, the cations and anions are linked through N-H⋯O hydrogen bonds. The thio-phene ring of the cation was found to be disordered over two sites, with refined occupancies of 0.798 (4) and 0.202 (4). ...[more]

PMID: 21589421

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