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{2-[(Benzo-yloxy)meth-yl]-1-oxo-3H-pyrrolizin-2-yl}methyl benzoate.

ABSTRACT: The title compound, C(23)H(19)NO(5), was prepared by esterification of 2,2-bis-(hy-droxy-meth-yl)-2,3-dihydro-1H-pyrrolizin-1-one with benzoyl chloride in pyridine·The pyrrolizine ring system is approximately planar with a maximum deviation of 0.008?(2)?Å from the least-squares plane; the two phenyl rings are oriented at dihedral angles of 64.26?(11) and 70.75?(10)° with respect to the pyrrolizine ring system. Weak inter-molecular C-H?O hydrogen bonding occurs in the crystal structure.

SUBMITTER: Ali Y

PROVIDER: S-EPMC3050358 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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{2-[(Benzo-yloxy)meth-yl]-1-oxo-3H-pyrrolizin-2-yl}methyl benzoate.

Ali Yousaf Y Yousuf Sammer S Afza Nighat N Peng Yu Y Kalhoro Mahboob Ali MA

Acta crystallographica. Section E, Structure reports online 20101218 Pt 1

The title compound, C(23)H(19)NO(5), was prepared by esterification of 2,2-bis-(hy-droxy-meth-yl)-2,3-dihydro-1H-pyrrolizin-1-one with benzoyl chloride in pyridine·The pyrrolizine ring system is approximately planar with a maximum deviation of 0.008 (2) Å from the least-squares plane; the two phenyl rings are oriented at dihedral angles of 64.26 (11) and 70.75 (10)° with respect to the pyrrolizine ring system. Weak inter-molecular C-H⋯O hydrogen bonding occurs in the crystal structure. ...[more]

PMID: 21522679

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