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Dichlorido(?-p-cymene)(4-fluoro-aniline-?N)ruthenium(II).

ABSTRACT: The title compound, [RuCl(2)(C(10)H(14))(C(6)H(6)FN)], a pseudo-octa-hedral d(6) complex, has the expected piano-stool geometry around the Ru(II) atom. The fluoro-aniline ring forms a dihedral angle of 19.3?(2)° with the p-cymene ring. In the crystal, two mol-ecules form an inversion dimer via a pair of N-H?Cl hydrogen bonds. Weak inter-molecular C-H?Cl inter-actions involving the p-cymene ring consolidate the crystal packing.

SUBMITTER: Sykora RE

PROVIDER: S-EPMC3050405 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Dichlorido(η-p-cymene)(4-fluoro-aniline-κN)ruthenium(II).

Sykora Richard E RE Harris Andrew G AG Clements Jason W JW Hoffman Norris W NW

Acta crystallographica. Section E, Structure reports online 20101218 Pt 1

The title compound, [RuCl(2)(C(10)H(14))(C(6)H(6)FN)], a pseudo-octa-hedral d(6) complex, has the expected piano-stool geometry around the Ru(II) atom. The fluoro-aniline ring forms a dihedral angle of 19.3 (2)° with the p-cymene ring. In the crystal, two mol-ecules form an inversion dimer via a pair of N-H⋯Cl hydrogen bonds. Weak inter-molecular C-H⋯Cl inter-actions involving the p-cymene ring consolidate the crystal packing. ...[more]

PMID: 21522611

Similar Datasets

Dichlorido(?(6)-p-cymene)(eth-oxy-diphenyl-phosphane)ruthenium(II).

Project description:The title compound, [RuCl2(C10H14)(C14H15OP)], is an Ru(II) complex in which an ?(6)-p-cymene ligand, two chloride anions and the P atom of an ethoxydiphenylphosphane ligand form a piano-stool coordination environment about the central Ru(II) atom.

| S-EPMC3588727 | biostudies-literature

p-Cymene Complexes of Ruthenium(II) as Antitumor Agents.

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Organometallic <i>cis</i>-Dichlorido Ruthenium(II) Ammine Complexes.

Project description:Bifunctional neutral half-sandwich RuII complexes of the type [(η6-arene)Ru(NH3)Cl2] where arene is p-cym (1) or bip (2) were synthesised by the reaction of N,N-dimethylbenzylamine (dmba), NH4PF6 and the corresponding RuII arene dimer, and were fully characterised. X-ray crystallographic studies of [(η6-p-cym)Ru(NH3)Cl2]·{(dmba-H)(PF6)} (1a) and [(η6-bip)Ru(NH3)Cl2] (2) show extensive H-bond interactions in the solid state, mainly involving the NH3 and the Cl ligands, as well as weak aromatic stacking interactions. The half-lives for the sequential hydrolysis of 1 and 2 determined by UV/Vis spectroscopy at 310 K ranged from a few minutes for the first aquation to ca. 45 min for the second aquation; the diaqua adducts were the predominant species at equilibrium. Arene loss during the aquation of complex 2 was observed. Upon hydrolysis, both complexes readily formed mono- and di-9-ethylguanine (9-EtG) adducts in aqueous solution at 310 K. The reaction reached equilibrium after ca. 1.8 h in the case of complex 1 and was slower but more complete for complex 2 (before the onset of arene loss at ca. 2.7 h). Complexes 1 and 2 were not cytotoxic towards A2780 human ovarian cancer cells up to the maximum concentration tested (100 μM).

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Bis(acrylonitrile-?N)dichlorido(?-cyclo-octa-1,5-diene)ruthenium(II).

Project description:In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(3)N)(2)], the metal ion is coordinated to centers of each of the double bonds of the cyclo-octa-1,5-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors from two acrylonitrile mol-ecules that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered octa-hedral with slight trigonal distortion. The three C atoms of one of the acrylonitrile ligands are disordered over two sets of sites in a 0.581?(13):0.419?(13) ratio.

| S-EPMC3201466 | biostudies-literature

Dichlorido(?-cyclo-octa-1,5-diene)bis-(propane-nitrile-?N)ruthenium(II).

Project description:In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(5)N)(2)], the metal ion is coordinated to both double bonds of the cyclo-octa-1,5-diene ligand, two chloride ions (in cis positions) and two N-atom donors from two propane-nitrile mol-ecules that complete the coordination sphere for the neutral complex. The coordination around the Ru(II) atom can thus be considered as octa-hedral with slight trigonal distortion.

| S-EPMC3201259 | biostudies-literature

Dicarbonyl-dichlorido(N,N,N',N'-tetra-methyl-ethylenediamine)-ruthenium(II).

Project description:In the title compound, [RuCl(2)(C(6)H(16)N(2))(CO)(2)], the geometry around the Ru(II) atom is a distorted RuC(2)N(2)Cl(2) octa-hedron, with pairs of C and Cl atoms trans to each other and the N atoms of the bidentate ligand in a cis conformation. The five-membered chelate ring is puckered on the C-C bond.

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(?(6)-Benzene)-dichlorido(dicyclo-hexyl-phenyl-phosphane)ruthenium(II) benzene sesquisolvate.

Project description:The asymmetric unit of the title compound, [RuCl2(C6H6)(C18H27P)]·1.5C6H6, contains one mol-ecule of the Ru(II) complex and one and a half solvent molecules as one of these is located about a centre of inversion. The Ru(II) atom has a classical three-legged piano-stool environment being coordinated by an ?(6)-benzene ligand [Ru-centroid = 1.6964?(6)?Å], two chloride ligands with an average Ru-Cl bond length of 2.4138?(3)?Å and a dicyclo-hexyl-phenyl-phosphane ligand [Ru-P = 2.3786?(3)?Å]. The effective cone angle for the phosphane was calculated to be 158°. In the crystal, weak C-H?Cl hydrogen bonds link the Ru(II) complexes into centrosymmetric dimers. The crystal packing exhibits intra- and inter-molecular C-H?? inter-actions resulting in a zigzag pattern in the [101] direction.

| S-EPMC3588713 | biostudies-literature

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