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Bis(acetonitrile-?N)dichlorido(?-cyclo-octa-1,5-diene)ruthenium(II) acetonitrile monosolvate.

ABSTRACT: In the title Ru(II) complex, [RuCl(2)(C(8)H(12))(C(2)H(3)N)(2)]·CH(3)CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo-octa-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN mol-ecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered to be octa-hedral with a slightly trigonal distortion. There is also one acetonitrile solvent mol-ecule per mol-ecule which is outside the coordination sphere of the ruthenium atom.

SUBMITTER: Chiririwa H 

PROVIDER: S-EPMC3212168 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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Bis(acetonitrile-κN)dichlorido(η-cyclo-octa-1,5-diene)ruthenium(II) acetonitrile monosolvate.

Chiririwa Haleden H   Meijboom Reinout R   Owalude Samson O SO   Eke Uche B UB   Arderne Charmaine C  

Acta crystallographica. Section E, Structure reports online 20110716 Pt 8

In the title Ru(II) complex, [RuCl(2)(C(8)H(12))(C(2)H(3)N)(2)]·CH(3)CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo-octa-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN mol-ecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered to be octa-hedral with a slightly trigonal distortion. There is also one acetonitrile solvent mol-ecule per mo  ...[more]

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