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Bis(acrylonitrile-?N)dichlorido(?-cyclo-octa-1,5-diene)ruthenium(II).

ABSTRACT: In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(3)N)(2)], the metal ion is coordinated to centers of each of the double bonds of the cyclo-octa-1,5-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors from two acrylonitrile mol-ecules that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered octa-hedral with slight trigonal distortion. The three C atoms of one of the acrylonitrile ligands are disordered over two sets of sites in a 0.581?(13):0.419?(13) ratio.

SUBMITTER: Chiririwa H 

PROVIDER: S-EPMC3201466 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Bis(acrylonitrile-κN)dichlorido(η-cyclo-octa-1,5-diene)ruthenium(II).

Chiririwa Haleden H   Meijboom Reinout R  

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

In the title complex, [RuCl(2)(C(8)H(12))(C(3)H(3)N)(2)], the metal ion is coordinated to centers of each of the double bonds of the cyclo-octa-1,5-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors from two acrylonitrile mol-ecules that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered octa-hedral with slight trigonal distortion. The three C atoms of one of the acrylonitrile ligands are disordered  ...[more]

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