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Dichlorido(furfuryl-amine-?N)(?-hexa-methyl-benzene)-ruthenium(II).

ABSTRACT: The single-crystal X-ray structure analysis of [RuCl(2)(C(12)H(18))(C(5)H(7)NO)] reveals a distorted piano-stool geometry around the Ru(II) atom, with a hexa-methyl-benzene ligand, two chloride ligands and a furfuryl-amine ligand, the latter coordinating through the amine group. In the crystal, a dimeric structure is observed as a result of N-H?Cl inter-actions between two symmetry-related mol-ecules.

SUBMITTER: Garci A 

PROVIDER: S-EPMC3247003 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Dichlorido(furfuryl-amine-κN)(η-hexa-methyl-benzene)-ruthenium(II).

Garci Amine A   Thai Trieu-Tien TT   Süss-Fink Georg G   Therrien Bruno B  

Acta crystallographica. Section E, Structure reports online 20111022 Pt 11

The single-crystal X-ray structure analysis of [RuCl(2)(C(12)H(18))(C(5)H(7)NO)] reveals a distorted piano-stool geometry around the Ru(II) atom, with a hexa-methyl-benzene ligand, two chloride ligands and a furfuryl-amine ligand, the latter coordinating through the amine group. In the crystal, a dimeric structure is observed as a result of N-H⋯Cl inter-actions between two symmetry-related mol-ecules. ...[more]

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